MSDS - 00231194

Material Safety Data Sheet
Material Name: ELMER'S PAINTERS - METALLIC
MSDS ID: 00231194
Issue Date: 12/07/09
Revision 1.0200

Other Sections
02 03 04 05 06 07 08 09 10 11 12 13 14 15 16

* * * Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION * * *

Material Name: ELMER'S PAINTERS - METALLIC

Manufacturer Information
Elmer's Products, Inc.
1 Easton Oval
Columbus, OH 43219

Emergency Phone Number:
Poison Control Center
1-888-516-2502

For additional product information, access our website at www.elmers.com or call 1-888-435-6377. To place an order, call 1-800-848-9400.

Product Use
paint related products

* * * Section 2 - HAZARDS IDENTIFICATION * * *

NFPA Ratings:
Health: 2 Fire: 3 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

EMERGENCY OVERVIEW
Physical Form: liquid
Odor: solvent odor
Major Health Hazards: respiratory tract irritation, skin irritation, eye irritation, central nervous system depression
Physical Hazards: Flammable liquid and vapor. Vapor may cause flash fire.
POTENTIAL HEALTH EFFECTS

Inhalation
Short Term: irritation, nausea, vomiting, loss of appetite, headache, drowsiness, dizziness, tremors, loss of coordination, lung congestion, heart damage, unconsciousness
Long Term: irritation, nausea, vomiting, headache, loss of appetite, drowsiness, dizziness, loss of coordination, tremors, nerve damage, unconsciousness

Skin
Short Term: irritation, absorption may occur, headache, drowsiness, dizziness, loss of coordination
Long Term: irritation, kidney damage

Eye
Short Term: irritation, tearing
Long Term: irritation, eye damage

Ingestion
Short Term: irritation, loss of appetite, nausea, vomiting, headache, drowsiness, dizziness, tremors, loss of coordination, lung congestion, heart damage, unconsciousness

* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *

CAS	Component	Percent
64742-95-6	LIGHT AROMATIC SOLVENT NAPHTHA	<=43.5
Not Available	NON-HAZARDOUS SUBSTANCE	<=27.5
64742-89-8	ALIPHATIC SOLVENT NAPHTHA	<=23.5
34590-94-8	DIPROPYLENE GLYCOL METHYL ETHER	<=5.5

* * * Section 4 - FIRST AID MEASURES * * *

Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.

Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.

Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

Ingestion
If a large amount is swallowed, get medical attention.

Note to Physicians
For inhalation, consider oxygen.

* * * Section 5 - FIRE FIGHTING MEASURES * * *

See Section 9 for Flammability Properties

Flammable Properties
Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures are explosive.

Extinguishing Media
carbon dioxide, regular dry chemical, regular foam, water

Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

Hazardous Combustion Products
Combustion: oxides of carbon

* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *

Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal.

* * * Section 7 - HANDLING AND STORAGE * * *

Storage Procedures
Store and handle in accordance with all current regulations and standards. Keep away from heat, sparks and flame. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding required. See original container for storage recommendations. Keep separated from incompatible substances.

* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *

Component Exposure Limits
DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

ACGIH:	100 ppm TWA
	150 ppm STEL
	Skin - potential significant contribution to overall exposure by the cutaneous route

NIOSH:	100 ppm TWA; 600 mg/m3 TWA
	150 ppm STEL; 900 mg/m3 STEL
	Potential for dermal absorption

OSHA:	100 ppm TWA; 600 mg/m3 TWA
	prevent or reduce skin absorption

OSHA (Vacated):	Prevent or reduce skin absorption
	150 ppm STEL; 900 mg/m3 STEL
	100 ppm TWA; 600 mg/m3 TWA

Ventilation
Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits.

Eyes/Face
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

Protective Clothing
Wear appropriate chemical resistant clothing.

Glove Recommendations
Wear appropriate chemical resistant gloves.

Protective Materials
protective skin cream

Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any chemical cartridge respirator with organic vapor cartridge(s).
Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s).
Any air-purifying respirator with a full facepiece and an organic vapor canister.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.

* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *

Physical State: Liquid	Appearance: Not available
Physical Form: liquid	Odor: solvent odor
Odor Threshold: Not available	pH: Not available
Melting/Freezing Point: Not available	Boiling Point: 120 - 199 °C
Flash Point: 13 °C (PMCC)	Evaporation Rate: >1 (butyl acetate=1)
OSHA Flammability Class: IB	LEL: 1.0 % (estimated)
UEL: 7.0 % (estimated)	Vapor Pressure: 6 mmHg (estimated)
Vapor Density (air = 1): >1	Density: Not available
Specific Gravity (water = 1): 0.9 - 1.0	Water Solubility: negligible
Coeff. Water/Oil Dist: Not available	Viscosity: Not available
Volatility: Not available

* * * Section 10 - STABILITY AND REACTIVITY * * *

Chemical Stability
Stable at normal temperatures and pressure.

Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers.

Materials to Avoid
oxidizing materials

Hazardous Decomposition
Combustion: oxides of carbon
Possibility of Hazardous Reactions
Will not polymerize.

* * * Section 11 - TOXICOLOGICAL INFORMATION * * *

Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:

LIGHT AROMATIC SOLVENT NAPHTHA (64742-95-6)

Inhalation LC50 Rat: >5.2 mg/L/4H; Inhalation LC50 Rat: 3400 ppm/4H; Oral LD50 Rat: 8400 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg

ALIPHATIC SOLVENT NAPHTHA (64742-89-8)

Oral LD50 Mouse: 5000 mg/kg; Dermal LD50 Rabbit: 3000 mg/kg

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

Oral LD50 Rat: 5230 mg/kg; Dermal LD50 Rabbit: 9500 mg/kg

RTECS Acute Toxicity (selected)
The components of this material have been reviewed, and RTECS publishes the following endpoints:

LIGHT AROMATIC SOLVENT NAPHTHA (64742-95-6)

Oral:

8400 mg/kg oral rat LD50

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

Oral:

5400 ul/kg oral rat LD50; 5.5 ml/kg oral rat LD50

Skin:

10 ml/kg skin rabbit LD50

Acute Toxicity Level
LIGHT AROMATIC SOLVENT NAPHTHA (64742-95-6)

Moderately Toxic:

inhalation.

Slightly Toxic:

ingestion.

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

Slightly Toxic:

dermal absorption, ingestion.

Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, OSHA, or NTP.

RTECS Irritation
The components of this material have been reviewed, and RTECS publishes the following endpoints:

LIGHT AROMATIC SOLVENT NAPHTHA (64742-95-6)

100 ul/24 hour(s) eyes rabbit mild

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

8 mg eyes human mild; 500 mg/24 hour(s) eyes rabbit mild; 500 mg/open skin rabbit mild

Local Effects
ALIPHATIC SOLVENT NAPHTHA (64742-89-8)

Irritant:

inhalation, skin, eye.

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

Irritant:

inhalation.

Target Organs
LIGHT AROMATIC SOLVENT NAPHTHA (64742-95-6)

central nervous system.

ALIPHATIC SOLVENT NAPHTHA (64742-89-8)

central nervous system.

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

central nervous system.

Medical Conditions Aggravated by Exposure
liver disorders, respiratory disorders

RTECS Tumorigenic
The components of this material have been reviewed, and RTECS publishes data for one or more components.

RTECS Mutagenic
The components of this material have been reviewed, and RTECS publishes data for one or more components.

RTECS Reproductive Effects
The components of this material have been reviewed, and RTECS publishes data for one or more components.

* * * Section 12 - ECOLOGICAL INFORMATION * * *

Component Analysis - Aquatic Toxicity
LIGHT AROMATIC SOLVENT NAPHTHA (64742-95-6)

Fish:

96 Hr LC50 Oncorhynchus mykiss: 9.22 mg/L

Invertebrate:

48 Hr EC50 Daphnia magna: 6.14 mg/L

ALIPHATIC SOLVENT NAPHTHA (64742-89-8)

Algae:

72 Hr EC50 Pseudokirchneriella subcapitata: 4700 mg/L

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

Fish:

96 Hr LC50 Pimephales promelas: >10000 mg/L [static]

Invertebrate:

48 Hr LC50 Daphnia magna: 1919 mg/L

* * * Section 13 - DISPOSAL CONSIDERATIONS * * *

Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.

Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.

* * * Section 14 - TRANSPORT INFORMATION * * *

US DOT Information
Shipping Name: Consumer commodity
Hazard Class: ORM-D
Required Label(s): None

TDG Information: No Classification assigned.

* * * Section 15 - REGULATORY INFORMATION * * *

U.S. Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan.

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

TSCA 12b:

Section 4, 1 %

SARA 311/312
Acute Health: Yes Chronic Health: No Fire: Yes Pressure: No Reactive: No

U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:

Component	CAS	CA	MA	MN	NJ	PA	RI
DIPROPYLENE GLYCOL METHYL ETHER	34590-94-8	Yes	Yes	Yes	Yes	Yes	Yes

Not regulated under California Proposition 65

Canada WHMIS
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:

DIPROPYLENE GLYCOL METHYL ETHER (34590-94-8)

1 %

U.S. Inventory (TSCA)
All the components of this substance are listed on or are exempt from the inventory.

Component Analysis - Inventory

Component	CAS	US	CA
LIGHT AROMATIC SOLVENT NAPHTHA	64742-95-6	Yes	DSL
ALIPHATIC SOLVENT NAPHTHA	64742-89-8	Yes	DSL
DIPROPYLENE GLYCOL METHYL ETHER	34590-94-8	Yes	DSL

* * * Section 16 - OTHER INFORMATION * * *

Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States

Other Information
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE
PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE,
except that the product shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind shall be greater in
amount than the purchase price of the quantity of product in respect of which damages are
claimed. In no event shall Seller be liable for incidental or consequential damages, whether
Buyer's claim is based on contract, breach of warranty, negligence or otherwise.