Material Safety Data Sheet
Material Name: Elmer's Glue-All Max
MSDS ID: ELM-038

Issue Date: 06/25/10
Revision 1.0000

Other Sections
02 03 04 05 06 07 08 09 10 11 12 13 14 15 16


* * * Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION * * *



Material Name: Elmer's Glue-All Max

Manufacturer Information
Elmer's Products, Inc.
1 Easton Oval
Columbus, OH 43219

Emergency Phone Number:
Poison Control Center
1-888-516-2502

For additional product information, access our website at www.elmers.com or call 1-888-435-6377. To place an order, call 1-800-848-9400.

Trade Names/Synonyms
E9406; E9415; E9416

Product Use
adhesives


* * * Section 2 - HAZARDS IDENTIFICATION * * *


NFPA Ratings:
Health: 2 Fire: 1 Reactivity: 1
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

EMERGENCY OVERVIEW
Color: brown
Physical Form: liquid
Odor: musty odor
Major Health Hazards: harmful if inhaled, respiratory tract irritation, skin irritation, eye irritation, allergic reactions
Physical Hazards: May react on contact with water.
POTENTIAL HEALTH EFFECTS

Inhalation
Short Term: irritation, allergic reactions, chest pain, difficulty breathing
Long Term: allergic reactions, difficulty breathing

Skin
Short Term: irritation, allergic reactions, skin disorders, itching, rash
Long Term: irritation, allergic reactions, rash, itching

Eye
Short Term: irritation
Long Term: irritation

Ingestion
Short Term: gastrointestinal irritation
Long Term: no information on significant adverse effects
OSHA Regulatory Status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).


* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *


CAS

Component

Percent

9016-87-9

POLYMETHYLENE POLYPHENYL ISOCYANATE

30-50

101-68-8

METHYLENE BISPHENYL ISOCYANATE

30-50

Not Available

NON-HAZARDOUS SUBSTANCE

10-30

108-90-7

CHLOROBENZENE

<0.01


* * * Section 4 - FIRST AID MEASURES * * *


Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.

Skin
If bonding occurs, immerse the bonded surfaces in warm soapy water. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing action. If burns occur, treat as thermal burns. Get medical attention, if needed.

Eyes
If bonding to tissues occurs, wash with large amounts of warm water. Cover both eyes with sterile, dry bandages. The eye will open without further action. Do not pull surfaces apart with a direct opposing action. If burns occur, treat as thermal burns. Get medical attention.

Ingestion
Wet lips with water. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing action. If a lump forms in the mouth, turn head to side. If burns occur, treat as thermal burns. Get medical attention.


Note to Physicians
For inhalation, consider oxygen.
Mineral oil, vegetable oil, or petroleum jelly may help soften the bonding between skin surfaces. For skin contact, consider acetone or nitromethane.


* * * Section 5 - FIRE FIGHTING MEASURES * * *


See Section 9 for Flammability Properties

Flammable Properties
Slight fire hazard.

Extinguishing Media
carbon dioxide, regular dry chemical, regular foam, water

Fire Fighting Measures
Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.


Hazardous Combustion Products
Combustion: cyanides, oxides of carbon, oxides of nitrogen


* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *


Occupational spill/release
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).


* * * Section 7 - HANDLING AND STORAGE * * *


Handling Procedures
Use only with adequate ventilation. Avoid breathing vapor or mist. Avoid prolonged or repeated contact with skin or eyes. Wash thoroughly after handling. Do not get in eyes.

Storage Procedures
Store and handle in accordance with all current regulations and standards. Keep container tightly closed. Store in a well-ventilated area. Avoid contact with water or moisture. Store between 16 C and 38 C. A hazardous build-up of pressure could result due to a reaction with water producing carbon dioxide gas if contaminated containers are resealed. Do not reseal contaminated containers. Reseal uncontaminated containers that are free of moisture only after placing under a nitrogen blanket. Do not store in containers made of copper, copper alloys, or galvanized surfaces. See original container for storage recommendations. Keep separated from incompatible substances.


* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *


Component Exposure Limits
METHYLENE BISPHENYL ISOCYANATE (101-68-8)

ACGIH:

0.005 ppm TWA

 

NIOSH:

0.005 ppm TWA; 0.05 mg/m3 TWA

0.020 ppm Ceiling (10 min); 0.2 mg/m3 Ceiling (10 min)

 

OSHA:

0.02 ppm Ceiling; 0.2 mg/m3 Ceiling

 

OSHA (Vacated):

0.02 ppm Ceiling; 0.2 mg/m3 Ceiling

CHLOROBENZENE (108-90-7)

ACGIH:

10 ppm TWA

 

OSHA:

75 ppm TWA; 350 mg/m3 TWA

 

OSHA (Vacated):

75 ppm TWA; 350 mg/m3 TWA


Ventilation
Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.

PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

Protective Clothing
Wear appropriate chemical resistant clothing.

Glove Recommendations
Wear appropriate chemical resistant gloves.

Protective Materials
neoprene, nitrile, butyl rubber

Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100.
Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100.
Any powered, air-purifying respirator with a high-efficiency particulate filter.
Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter.
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.


* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *


Physical State: Liquid

Appearance: Brown liquid

Color: brown

Physical Form: liquid

Odor: musty odor

Odor Threshold: Not available

pH: Not available

Melting/Freezing Point: Not available

Boiling Point: >300 °C (decomposes)

Flash Point: >110 °C (CC)

Evaporation Rate: Not available

OSHA Flammability Class: IIIB

Vapor Pressure: 0.000004 mmHg

Vapor Density (air = 1): 8.5

Density: Not available

Specific Gravity (water = 1): 1.129

Water Solubility: reacts, immiscible

Coeff. Water/Oil Dist: Not available

Auto Ignition: >600 °C

Viscosity: 2311 cP

Volatility: Not available




* * * Section 10 - STABILITY AND REACTIVITY * * *


Chemical Stability
May react on contact with water. Closed containers may rupture.

Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.

Materials to Avoid
acids, alcohols, amines, bases, combustible materials, metal salts, metals, oxidizing materials


Hazardous Decomposition
Water or Moisture: oxides of carbon

Hazardous Decomposition
Combustion: cyanides, oxides of carbon, oxides of nitrogen
Possibility of Hazardous Reactions
Polymerization may occur in the presence of metal compounds, alkalies, and tertiary amines at elevated temperatures.


* * * Section 11 - TOXICOLOGICAL INFORMATION * * *


Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published:

POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

Inhalation LC50 Rat 490 mg/m3 4 h; Oral LD50 Rat 49 g/kg; Dermal LD50 Rabbit >9400 mg/kg

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

Oral LD50 Rat 9200 mg/kg

CHLOROBENZENE (108-90-7)

Oral LD50 Rat 1110 mg/kg


RTECS Acute Toxicity (selected)
The components of this material have been reviewed, and RTECS publishes the following endpoints:

POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

Inhalation:

490 mg/m3/4 hour Inhalation Rat LC50

 

Oral:

49 gm/kg Oral Rat LD50

 

Skin:

>9400 mg/kg Skin Rabbit LD50

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

Inhalation:

178 mg/m3 Inhalation Rat LC50

 

Oral:

9200 mg/kg Oral Rat LD50


Acute Toxicity Level
POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

Highly Toxic:

inhalation.

 

Non Toxic:

ingestion.

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

Highly Toxic:

inhalation.

 

Slightly Toxic:

ingestion.

CHLOROBENZENE (108-90-7)

Moderately Toxic:

inhalation, ingestion.


Component Carcinogenicity
POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

IARC:

Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

IARC:

Monograph 71 [1999]; Supplement 7 [1987]; Monograph 19 [1979] (Group 3 (not classifiable))

CHLOROBENZENE (108-90-7)

ACGIH:

A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans


Irritation
See component data.

RTECS Irritation
The components of this material have been reviewed, and RTECS publishes the following endpoints:

POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

100 mg Eyes Rabbit mild

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

100 mg Eyes Rabbit moderate; 500 mg/24 hour Skin Rabbit


Local Effects
POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

Irritant:

inhalation, skin, eye.

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

Irritant:

inhalation, skin, eye.

CHLOROBENZENE (108-90-7)

Irritant:

inhalation, skin, eye.


Target Organs
POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

immune system (sensitizer).

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

immune system (sensitizer).

CHLOROBENZENE (108-90-7)

central nervous system.


Medical Conditions Aggravated by Exposure
respiratory system (including asthma and other breathing disorders), skin disorders

RTECS Tumorigenic
The components of this material have been reviewed, and RTECS publishes data for one or more components.

RTECS Mutagenic
The components of this material have been reviewed, and RTECS publishes data for one or more components.

RTECS Reproductive Effects
The components of this material have been reviewed, and RTECS publishes data for one or more components.

Additional Data
May cross react with similar compounds.


* * * Section 12 - ECOLOGICAL INFORMATION * * *


Component Analysis - Aquatic Toxicity
CHLOROBENZENE (108-90-7)

Fish:

96 Hr LC50 Pimephales promelas: 7-8.5 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: 4.5 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: 6.9-7.9 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 4.1-4.9 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss: 4.1-5.3 mg/L [flow-through]; 96 Hr LC50 Brachydanio rerio: 91 mg/L [static]; 96 Hr LC50 Poecilia reticulata: 36.35-58.19 mg/L [static]

 

Algae:

96 Hr EC50 Pseudokirchneriella subcapitata: 2.55 - 420 mg/L; 96 Hr EC50 Pseudokirchneriella subcapitata: 12.5 mg/L [static]

 

Invertebrate:

48 Hr EC50 Daphnia magna: 0.59 mg/L

 


* * * Section 13 - DISPOSAL CONSIDERATIONS * * *


Disposal Methods
Dispose in accordance with all applicable regulations.

Component Waste Numbers
CHLOROBENZENE (108-90-7)

RCRA:

waste_number U037

100.0 mg/L regulatory level

 


* * * Section 14 - TRANSPORT INFORMATION * * *


US DOT Information: No Classification assigned.
TDG Information: No Classification assigned.


* * * Section 15 - REGULATORY INFORMATION * * *


U.S. Federal Regulations
This material contains one or more of the following chemicals required to be identified under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan.

POLYMETHYLENE POLYPHENYL ISOCYANATE (9016-87-9)

SARA 313:

1.0 % de minimis concentration

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

SARA 313:

1.0 % de minimis concentration

 

CERCLA:

5000 lb final RQ; 2270 kg final RQ

CHLOROBENZENE (108-90-7)

SARA 313:

1.0 % de minimis concentration

 

CERCLA:

100 lb final RQ; 45.4 kg final RQ

 

TSCA 12b:

Section 4, 1 %



SARA 311/312
Acute Health: Yes Chronic Health: Yes Fire: No Pressure: No Reactive: No

U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:

Component

CAS

CA

MA

MN

NJ

PA

RI

POLYMETHYLENE POLYPHENYL ISOCYANATE

9016-87-9

No

No

No

Yes

No

No

METHYLENE BISPHENYL ISOCYANATE

101-68-8

Yes

Yes

Yes

Yes

Yes

Yes

CHLOROBENZENE

108-90-7

Yes

Yes

Yes

Yes

Yes

Yes

Not regulated under California Proposition 65

Canada WHMIS
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:

METHYLENE BISPHENYL ISOCYANATE (101-68-8)

0.1 %


U.S. Inventory (TSCA)
All the components of this substance are listed on or are exempt from the inventory.

Component Analysis - Inventory

Component

CAS

US

CA

POLYMETHYLENE POLYPHENYL ISOCYANATE

9016-87-9

Yes

DSL

METHYLENE BISPHENYL ISOCYANATE

101-68-8

Yes

DSL

CHLOROBENZENE

108-90-7

Yes

DSL


* * * Section 16 - OTHER INFORMATION * * *


Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States

Other Information
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE
PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE,
except that the product shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind shall be greater in
amount than the purchase price of the quantity of product in respect of which damages are
claimed. In no event shall Seller be liable for incidental or consequential damages, whether
Buyer's claim is based on contract, breach of warranty, negligence or otherwise.


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New MSDS: 6/24/2010