Material Safety Data Sheet
Material Name: ELMER'S NO-WRINKLE RUBBER CEMENT
MSDS ID: 00229810
Issue Date: 12/16/10
Revision 1.0400
Other Sections
02 03 04 05
06 07 08 09
10 11 12 13
14 15 16
* * * Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name: ELMER'S NO-WRINKLE RUBBER CEMENT
Manufacturer Information
Elmer's Products, Inc.
1 Easton Oval
Columbus, OH 43219
Emergency Phone Number:
Poison Control Center
1-888-516-2502
For additional product information, access our website at www.elmers.com or call 1-888-435-6377. To place an order, call 1-800-848-9400.
Trade Names/Synonyms
E904; E905; 231; 232; 233; 60818; 61518
Product Use
adhesives
* * * Section 2 - HAZARDS IDENTIFICATION * * *
NFPA Ratings:
Health: 2 Fire: 3 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
EMERGENCY OVERVIEW
Physical Form: liquid
Odor: mild odor, solvent odor
Major Health Hazards: potentially fatal if swallowed, respiratory tract
irritation, skin irritation, eye irritation, central nervous system depression,
allergic reactions
Physical Hazards: Flammable liquid and vapor. Vapor may cause flash
fire.
POTENTIAL HEALTH EFFECTS
Inhalation
Short Term: irritation, changes in blood pressure, nausea, vomiting,
stomach pain, chest pain, difficulty breathing, irregular heartbeat, headache,
drowsiness, dizziness, disorientation, emotional disturbances, hallucinations,
loss of coordination, suffocation, internal bleeding, kidney damage,
unconsciousness, coma
Long Term: no information on significant adverse effects
Skin
Short Term: irritation, allergic reactions, absorption may occur,
changes in blood pressure, nausea, vomiting, irregular heartbeat, headache,
drowsiness, dizziness, loss of coordination
Long Term: irritation
Eye
Short Term: irritation, eye damage
Long Term: irritation
Ingestion
Short Term: potentially fatal if swallowed, irritation, changes in blood
pressure, nausea, vomiting, diarrhea, stomach pain, difficulty breathing,
irregular heartbeat, headache, drowsiness, dizziness, disorientation, emotional
disturbances, hallucinations, loss of coordination, internal bleeding, kidney
damage, unconsciousness, coma
Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
|
CAS |
Component |
Percent |
|
142-82-5 |
HEPTANE |
>70 |
|
67-63-0 |
ISOPROPYL ALCOHOL |
1-5 |
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information
identified as the following: Heptane isomers.
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial
respiration if not breathing. Get immediate medical attention.
Skin
If bonding occurs, immerse the bonded surfaces in warm soapy water. Peel or
roll the surfaces apart using a blunt edge, such as a spatula or spoon handle.
Do not pull surfaces apart with a direct opposing action. If burns occur, treat
as thermal burns. Get medical attention, if needed.
Eyes
If bonding to tissues occurs, wash with large amounts of warm water. Cover both
eyes with sterile, dry bandages. The eye will open without further action. Do
not pull surfaces apart with a direct opposing action. If burns occur, treat as
thermal burns. Get medical attention.
Ingestion
Wet lips with water. Peel or roll the surfaces apart using a blunt edge, such
as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing
action. If a lump forms in the mouth, turn head to side. If burns occur, treat
as thermal burns. Get medical attention.
Note to Physicians
Mineral oil, vegetable oil, or petroleum jelly may help soften the bonding
between skin surfaces. For skin contact, consider acetone or nitromethane.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
Flammable Properties
Severe fire hazard. The vapor is heavier than air. Vapors or gases may ignite
at distant ignition sources and flash back. Vapor/air mixtures are explosive.
Extinguishing Media
carbon dioxide, regular dry chemical, regular foam, water
Fire Fighting Measures
Move container from fire area if it can be done without risk. Cool containers
with water spray until well after the fire is out. Flood with fine water spray.
Do not scatter spilled material with high-pressure water streams. Avoid
inhalation of material or combustion by-products. Stay upwind and keep out of
low areas.
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small spills:
Absorb with sand or other non-combustible material. Collect spilled material in
appropriate container for disposal.
* * * Section 7 - HANDLING AND STORAGE * * *
Storage Procedures
Store and handle in accordance with all current regulations and standards.
Store in a cool, dry place. Store in a tightly closed container. Store in a
well-ventilated area. Avoid heat, flames, sparks and other sources of ignition.
Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding and
bonding required. See original container for storage recommendations. Keep
separated from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
HEPTANE (142-82-5)
|
ACGIH: |
400 ppm TWA |
|
500 ppm STEL |
|
NIOSH: |
85 ppm TWA; 350 mg/m3 TWA |
|
440 ppm Ceiling (15 min); 1800 mg/m3 Ceiling (15 min) |
|
OSHA: |
500 ppm TWA; 2000 mg/m3 TWA |
|
OSHA (Vacated): |
500 ppm STEL; 2000 mg/m3 STEL |
|
400 ppm TWA; 1600 mg/m3 TWA |
ISOPROPYL ALCOHOL (67-63-0)
|
ACGIH: |
200 ppm TWA |
|
400 ppm STEL |
|
NIOSH: |
400 ppm TWA; 980 mg/m3 TWA |
|
500 ppm STEL; 1225 mg/m3 STEL |
|
OSHA: |
400 ppm TWA; 980 mg/m3 TWA |
|
OSHA (Vacated): |
500 ppm STEL; 1225 mg/m3 STEL |
|
400 ppm TWA; 980 mg/m3 TWA |
Ventilation
Ventilation equipment should be explosion-resistant if explosive concentrations
of material are present. Provide local exhaust or process enclosure ventilation
system. Ensure compliance with applicable exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face
Wear splash resistant safety goggles with a faceshield. Provide an emergency
eye wash fountain and quick drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may
be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any chemical cartridge respirator with organic vapor cartridge(s).
Any chemical cartridge respirator with a full facepiece and organic vapor
cartridge(s).
Any air-purifying respirator with a full facepiece and an organic vapor
canister.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a
pressure-demand or other positive-pressure mode in combination with an
auxiliary self-contained breathing apparatus operated in pressure-demand or
other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is
operated in a pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
|
Physical State: Liquid |
Appearance: opaque |
|
Physical Form: liquid |
Odor: mild odor, solvent odor |
|
Odor Threshold: Not available |
pH: Not available |
|
Melting/Freezing Point: Not available |
Boiling Point: 90 °C |
|
Flash Point: -4 °C (TCC) |
Evaporation Rate: <1 (ether=1)> |
|
OSHA Flammability Class: IB |
Vapor Pressure: Not available |
|
Vapor Density (air = 1): >1 |
Density: Not available |
|
Specific Gravity (water = 1): 0.71 |
Water Solubility: almost insoluble |
|
Coeff. Water/Oil Dist: Not available |
Viscosity: Not available |
|
Volatility: 90 % |
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Stable at normal temperatures and pressure.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Containers may
rupture or explode if exposed to heat. Keep out of water supplies and sewers.
Materials to Avoid
acids, bases, amines, oxidizing materials
Decomposition Products
oxides of carbon
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the
following selected endpoints are published:
HEPTANE (142-82-5)
|
Inhalation LC50 Rat 103 g/m3 4 h; Oral LD50 Mouse 5000 mg/kg; Dermal LD50 Rabbit 3000 mg/kg |
ISOPROPYL ALCOHOL (67-63-0)
|
Inhalation LC50 Rat 72.6 mg/L 4 h; Oral LD50 Rat 4396 mg/kg; Dermal LD50 Rat 12800 mg/kg; Dermal LD50 Rabbit 12870 mg/kg |
RTECS Acute Toxicity (selected)
The components of this material have been reviewed, and RTECS publishes the
following endpoints:
HEPTANE (142-82-5)
|
Inhalation: |
103 gm/m3/4 hour Inhalation Rat LC50; 48000 ppm/4 hour Inhalation Rat LC50; >29290 mg/m3 Inhalation Rat LC50 |
ISOPROPYL ALCOHOL (67-63-0)
|
Inhalation: |
16000 ppm/8 hour Inhalation Rat LC50; 72600 mg/m3 Inhalation Rat LC50 |
|
Oral: |
5000 mg/kg Oral Rat LD50; 5045 mg/kg Oral Rat LD50 |
|
Skin: |
12800 mg/kg Skin Rabbit LD50 |
Acute Toxicity Level
HEPTANE (142-82-5)
|
Slightly Toxic: |
inhalation. |
ISOPROPYL ALCOHOL (67-63-0)
|
Moderately Toxic: |
inhalation, ingestion. |
|
Slightly Toxic: |
dermal absorption. |
Component Carcinogenicity
ISOPROPYL ALCOHOL (67-63-0)
|
ACGIH: |
A4 - Not Classifiable as a Human Carcinogen |
|
IARC: |
Monograph 71 [1999]; Supplement 7 [1987]; Monograph 15 [1977] (Group 3 (not classifiable)) |
RTECS Irritation
The components of this material have been reviewed, and RTECS publishes the
following endpoints:
ISOPROPYL ALCOHOL (67-63-0)
|
10 mg Eyes Rabbit moderate; 100 mg/24 hour Eyes Rabbit moderate; 100 mg Eyes Rabbit severe; 500 mg Skin Rabbit mild |
Local Effects
HEPTANE (142-82-5)
|
Irritant: |
inhalation, skin, eye. |
ISOPROPYL ALCOHOL (67-63-0)
|
Irritant: |
inhalation, eye. |
Target Organs
HEPTANE (142-82-5)
|
central nervous system. |
ISOPROPYL ALCOHOL (67-63-0)
|
central nervous system. |
Medical Conditions Aggravated by Exposure
respiratory disorders, kidney disorders, skin disorders and allergies, liver
disorders
RTECS Tumorigenic
The components of this material have been reviewed, and RTECS publishes data
for one or more components.
RTECS Mutagenic
The components of this material have been reviewed, and RTECS publishes data
for one or more components.
RTECS Reproductive Effects
The components of this material have been reviewed, and RTECS publishes data
for one or more components.
Additional Data
Stimulants such as epinephrine may induce ventricular fibrillation.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
HEPTANE (142-82-5)
|
Fish: |
96 Hr LC50 Cichlid fish: 375.0 mg/L |
|
Invertebrate: |
24 Hr EC50 Daphnia magna: >10 mg/L |
ISOPROPYL ALCOHOL (67-63-0)
|
Fish: |
96 Hr LC50 Pimephales promelas: 9640 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: 11130 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: >1400000 µg/L |
|
Algae: |
96 Hr EC50 Desmodesmus subspicatus: >1000 mg/L; 72 Hr EC50 Desmodesmus subspicatus: >1000 mg/L |
|
Invertebrate: |
48 Hr EC50 Daphnia magna: 13299 mg/L |
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal
regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information
Shipping Name: Consumer commodity
Hazard Class: ORM-D
Required Label(s): None
TDG Information: No Classification assigned.
* * * Section 15 - REGULATORY INFORMATION * * *
U.S. Federal Regulations
This material contains one or more of the following chemicals required to be
identified under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section
313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA
process safety plan.
HEPTANE (142-82-5)
|
TSCA 12b: |
Section 4, 1 % |
ISOPROPYL ALCOHOL (67-63-0)
|
SARA 313: |
1.0 % de minimis concentration (only if manufactured by the strong acid process, no supplier notification) |
SARA 311/312
Acute Health: Yes Chronic Health: No Fire: Yes Pressure:
No Reactive: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous
substances lists:
|
Component |
CAS |
CA |
MA |
MN |
NJ |
PA |
RI |
|
HEPTANE |
142-82-5 |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
|
ISOPROPYL ALCOHOL |
67-63-0 |
Yes |
Yes |
Yes |
Yes |
Yes |
Yes |
Not regulated under California Proposition 65
Canada WHMIS
The following components are identified under the Canadian Hazardous Products
Act Ingredient Disclosure List:
HEPTANE (142-82-5)
|
1 % |
ISOPROPYL ALCOHOL (67-63-0)
|
1 % |
WHMIS Classification
D2B, B2.
Canadian Inventory
All components of this product are listed on the DSL.
U.S. Inventory (TSCA)
All the components of this substance are listed on or are exempt from the
inventory.
Component Analysis - Inventory
|
Component |
CAS |
US |
CA |
|
HEPTANE |
142-82-5 |
Yes |
DSL |
|
ISOPROPYL ALCOHOL |
67-63-0 |
Yes |
DSL |
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR -
European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C -
Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive
Environmental Response, Compensation, and Liability Act; CN - China; CPR -
Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT -
Department of Transportation; DSL - Domestic Substances List; EEC - European
Economic Community; EINECS - European Inventory of Existing Commercial Chemical
Substances; EPA - Environmental Protection Agency; EU - European Union; F -
Fahrenheit; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; ICAO - International Civil Aviation Organization;
IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and
Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow -
Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit;
LOLI - List Of LIsts™ - ChemADVISOR's Regulatory Database; MAK - Maximum
Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA -
National Fire Protection Agency; NIOSH - National Institute for Occupational
Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National
Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health
Administration; PH - Philippines; RCRA - Resource Conservation and Recovery
Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical
Substances®; SARA - Superfund Amendments and Reauthorization Act; STEL -
Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA -
Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper
Explosive Limit; US - United States
Other Information
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE
PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE,
except that the product shall conform to contracted specifications, and that
the product does not
infringe any valid United States or Canadian patent. No claim of any kind shall
be greater in
amount than the purchase price of the quantity of product in respect of which
damages are
claimed. In no event shall Seller be liable for incidental or consequential damages,
whether
Buyer's claim is based on contract, breach of warranty, negligence or
otherwise.
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