Material Safety Data Sheet

F


1. Chemical Product and Company Identification

 
     DESCRIPTION:     CARPENTERS WOOD FILLER TUBES (ALL COLORS)
     PRODUCT TYPE:    MODIFIED PVAC
     APPLICATION:     FOR PRODUCT CODES, SEE SECTION 16

         Manufacturer/Supplier Information

 
     MSDS Prepared by:
     Elmer's Products, Inc.                           Emergency Phone Number
     1 Easton Oval                                    Poison Control Center
     Columbus, OH  43219                              1-888-516-2502
     For additional health, safety or regulatory information, call 1-888-435-6377.
     Call 1-800-848-9400 to place an order or request additional MSDSs.

2. Composition, Information on Ingredients

 
     The ingredients listed below have been associated with one or more
     immediate and/or delayed(*) health hazards.  Risk of damage and effects
     depends upon duration and level of exposure.  BEFORE USING, HANDLING, OR
     EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.
                                                                     % by weight
        546-93-0 Magnesium Carbonate (MgCO3)                                1-5
       1317-65-3 *Limestone                                                30-50
       1332-58-7 *Kaolin                                                    1-5
       1333-86-4 *Carbon Black                                            0.1-0.99
      14808-60-7 *Quartz (SiO2)                                           0.1-0.99

3. Hazards Identification

 

3.1 Emergency Overview

 
     Appearance                          Soft paste
     Odor                                Mild
     CAUTION!
     Not a significant fire hazard.
     May cause eye irritation

         HMIS Rating

 
           HEALTH = 1 (slight)
     FLAMMABILITY = 0 (minimal)
       REACTIVITY = 0 (minimal)
          CHRONIC = *

3.2 Potential Health Effects

 

         Immediate Hazards

 
     INGESTION:   No hazards known to company.
     INHALATION:  Not expected to be harmful under normal conditions of
                  use.  However, if allowed to become airborne, may cause
                  irritation of nose, throat and lungs.
     SKIN:        May cause irritation on prolonged or repeated contact.
     EYES:        May cause irritation on prolonged or repeated contact.
     

         Delayed Hazards

 
     Limestone      1317-65-3     
     Can cause lung damage.  Pre-existing respiratory disorders may be
     aggravated by exposure.
     -- See Footnote C.
     Kaolin      1332-58-7     
     Chronic inhalation has resulted in benign pneumoconiosis.
     Pre-existing respiratory disorders may be aggravated by exposure.
     -- See Footnote C.
     Carbon Black      1333-86-4     
     POSSIBLE CANCER HAZARD.  May cause cancer based on animal data.  This
     material has been classified by IARC as an animal carcinogen (Group
     2B).  This material is not listed by NTP nor regulated by OSHA as a
     carcinogen.
     Chronic inflammation, lung fibrosis and lung tumors have been observed
     in some rats exposed for long periods of time to excessive
     concentrations of carbon black and several other insoluble fine dust
     particles which overwhelm the lung clearance mechanisms.  Tumors have
     not been observed in other animal species similarly tested.  Studies
     in both the carbon black production industry and some user industries
     suggest that there is inadequate evidence that carbon black causes
     cancer in humans.
     Quartz (SiO2)     14808-60-7     
     CANCER HAZARD.  Can cause cancer.  Use of this product may
     generate silica dust (which may be invisible).  Inhaled silica has
     been classified by IARC as a human carcinogen.
     Footnote C:  As of the date of issuance of this document, this
     material has not been listed by NTP, classified by IARC nor regulated
     by OSHA as a carcinogen.

4. First Aid Measures

 
     INGESTION:   If accidentally swallowed, dilute by drinking large
                  quantities of water.  Immediately contact poison control
                  center or hospital emergency room for any other
                  additional treatment directions.
     INHALATION:  Remove to fresh air.
     SKIN:         In case of irritation, flush with water.
     EYES:        Immediately flush eyes with plenty of water.  Call
                  a physician if irritation persists.

5. Fire Fighting Measures

 
     Autoignition Temperature            Not available
     Upper/Lower Flammable Limits        Not applicable
     Up/Lower Explosive Limits, % by Vol Not applicable
     Flash Point                         Not applicable
     Will not burn unless water has evaporated.  Dried material may
     burn.
     In case of fire, water should be used to keep fire-exposed
     containers cool.

6. Accidental Release Measures

 
     Sweep (scoop) up and remove to a chemical disposal area.  Prevent
     entry into natural bodies of water.

7. Handling and Storage

 

7.1 Handling

 
     Handle in accordance with good industrial hygiene and safety
     practices.  These practices include avoiding unnecessary exposure and
     removal of the material from eyes, skin and clothing.
     Wash thoroughly after handling.  Always use appropriate Personal
     Protective Equipment (PPE).
     INHALATION:  Avoid prolonged or repeated breathing of vapor.
     SKIN:  Avoid prolonged or repeated contact with skin and clothing.
     EYES:  Avoid prolonged or repeated contact with eyes.

7.2 Storage

 
     Keep from freezing.
     Store in a cool, dry place.
     Keep containers tightly closed.

8. Exposure Controls/Personal Protection

 

8.1 Exposure Controls

 
     If airborne contaminants are generated when the material is heated or
     handled, sufficient ventilation in volume and air flow patterns should
     be provided to keep air contaminant concentration levels below
     acceptable criteria.

8.2 Personal Protection

 
     Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA
     approved respiratory protection equipment.  Respirators should be
     selected based on the form and concentration of contaminants in air
     in accordance with OSHA laws and regulations or other applicable
     standards or guidelines, including ANSI standards regarding
     respiratory protection.  Use goggles if contact is likely.  Wear
     impervious gloves as required to prevent skin contact.

8.3 Exposure Guidelines

 
     Magnesium Carbonate (MgCO3)       546-93-0     
     ACGIH TLV: 10 mg/m TWA, inhalable particulate
     OSHA PEL: 5 mg/m TWA, particulates respirable; 15 mg/m TWA
     total dust
     Limestone      1317-65-3     
     ACGIH TLV: 10 mg/m TWA, inhalable particulate
     OSHA PEL: 5 mg/m TWA, respirable particulates; 15 mg/m TWA
     total dust
     Kaolin      1332-58-7     
     ACGIH TLV: 2 mg/m TWA, respirable fraction
     OSHA PEL: 15 mg/m TWA, total dust; 5 mg/m TWA, respirable
     fraction
     REMANDED PEL: 10 mg/ TWA, total dust; 5 mg/m TWA,
     respirable fraction
     OSHA 1989 PEL remanded, but in effect in some states
     Carbon Black      1333-86-4     
     ACGIH TLV: 3.5 mg/m TWA
     OSHA PEL: 3.5 mg/m TWA
     Quartz (SiO2)     14808-60-7     
     ACGIH TLV: 0.05 mg/m TWA, respirable fraction, A2 - See Appendix A
     OSHA PEL: 10/(%SiO2 + 2) mg/m TWA, respirable dust;
     30/(%SiO2 + 2) mg/m TWA, total dust
     REMANDED PEL: 0.1 mg/m TWA, respirable dust
     OSHA 1989 PEL remanded, but in effect in some states
     OTHER: NIOSH has recommended a permissible exposure limit of 50 micrograms
     respirable free silica per cubic meter of air (0.05 mg/m) averaged
     over a workshift of up to 10 hours per day, 40 hours per week.  NIOSH
     publications, including the NIOSH Criteria Document for Crystalline
     Silica, should be consulted for more detailed information.

9. Physical and Chemical Properties

 
     Percent Volatiles                   22
     pH @ 25 C                           9.5
     Specific Gravity                    1.34
     Appearance                          Soft paste
     Autoignition Temperature            Not available
     Boiling Point                       100C (212F)
     Vapor Density (Air=1)               <1
     Vapor Pressure, mm Hg @ 20 C        17
     Evaporation Rate (Butyl Acetate=1)  <1
     Upper/Lower Flammable Limits        Not applicable
     Up/Lower Explosive Limits, % by Vol Not applicable
     Flash Point                         Not applicable
     Freezing Point                      0C (32F)
     Odor                                Mild
     Odor Threshold, ppm                 Not available
     Solubility in Water                 Dispersible

10. Stability and Reactivity

 
     Normally stable as defined in NFPA 704-12(4-3.1).

         Incompatibilities:

 
     None known to company.

         Decomposition products may include:

 
     Acrylic monomers by thermal decomposition.

         Hazardous polymerization:

 
     Will not occur.

         Other Hazards:

 
     None known to company.

11. Toxicological Information

 
     See Section 3 Hazards Identification information.
     Magnesium Carbonate (MgCO3)       546-93-0     
     LC50: Not available
     LD50: Not available
     Limestone      1317-65-3     
     LC50: Not available
     LD50: Not available
     Kaolin      1332-58-7     
     LC50: Not available
     LD50: Not available
     Carbon Black      1333-86-4     
     LC50: Not available
     LD50: Not available
     Quartz (SiO2)     14808-60-7     
     LC50: Not available
     LD50: Not available

12. Ecological Information

 
     Not determined.

13. Disposal Considerations

 
     Dispose of according to local, state/provincial, and federal
     requirements.

14. Transport Information

 

14.1 U.S. Department of Transportation (DOT)

 
     The data provided in this section is for information only and may not
     be specific to your package size.  You will need to apply the
     appropriate regulations to properly classify your shipment for
     transportation.
     Non-Regulated.

14.2 Canadian Transportation of Dangerous Goods (TDG)

 
     Non-Regulated.

15. Regulatory Information (Selected Regulations)

 

15.1 U.S. Federal Regulations

 

         OSHA Hazard Communication Standard 29CFR1910.1200

 
     This material presents possible health hazards as determined when
     reviewed according to the requirements of the Occupational Safety and
     Health Administration 29 CFR Part 1910.1200 "Hazard Communication"
     Standard.

         SARA Title III: Section 311/312

 
     Delayed health hazard

         SARA Title III Section 313 and 40 CFR Part 372

 
     This product contains the following toxic chemical(s) subject to the
     reporting requirements of Section 313 of Title III of the Superfund
     Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
     Notification Requirement of 40 CFR Part 372.
     None required per SARA TITLE III SECTION 313.

         TSCA Section 8(b) Inventory

 
     All reportable chemical substances are listed on the TSCA Inventory.
     We rely on certifications of compliance from our suppliers for
     chemical substances not manufactured by us.

15.2 Canadian Regulations

 

         Workplace Hazardous Materials Information System (WHMIS)

 
     This product has been classified in accordance with the hazard
     criteria of the Controlled Products Regulation (CPR) and the MSDS
     contains all the information required by the CPR.
          CLASS D, DIV 2A, 2B      

         Canadian Environmental Protection Act (CEPA)

 
     All reportable chemical substances are listed on the Domestic
     Substances List (DSL) or otherwise comply with CEPA new substance
     notification requirements.

         National Pollutant Release Inventory (NPRI)

 
     This product contains the following chemical(s) subject to the
     reporting requirements of the Canadian Environmental Protection Act
     (CEPA) subsection 16(1), National Pollutant Release Inventory.
     None required.

16. Other Information

 
     CL (Cautionary Labeling): Products bearing the CL (Cautionary
     Labeling) Seal of The Art & Creative Materials Institute, Inc. (ACMI)
     are certified to be properly labeled in a program of toxicological
     evaluation by a medical expert. This program is reviewed by ACMI's
     Toxicological Advisory Board. These products are certified by ACMI
     to be labeled in accordance with the chronic hazard labeling
     standard, ASTM D-4236 and Federal Law, P.L. 100-695.
     MSDS covers items:
     U.S.:    E855, E859, E860, E861, E864, E868
     Canada:  60853, 60854, 60859, 60860, 60864, 60868

         User's Responsibility

 
     The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
     Hazardous Materials Information System (WHMIS) require that the information
     contained on these sheets be made available to your workers.  Educate and
     train your workers regarding OSHA and WHMIS precautions.  Instruct your
     workers to handle this product properly.  Consult with appropriate experts
     to guard against hazards associated with use of this product and its
     ingredients.

         Disclaimer

 
     SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
     MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
     shall conform to contracted specifications, and that the product does not
     infringe any valid United States or Canadian patent.  No claim of any kind
     shall be greater in amount than the purchase price of the quantity of
     product in respect of which damages are claimed.  In no event shall Seller
     be liable for incidental or consequential damages, whether Buyer's claim is
     based on contract, breach of warranty, negligence or otherwise.

 
                                                  CURRENT ISSUE: 26-OCT-10
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