MATERIAL SAFETY DATA SHEET


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


Elmer's Products, Inc.

Emergency Phone Number:

1 Easton Oval

Poison Control Center

Columbus, OH 43219

1-888-516-2502


For additional product information, access our website at www.elmers.com or call 1-888-435-6377. To place an order, call 1-800-848-9400.

SUBSTANCE: ELMER'S PLASTIC CEMENT

TRADE NAMES/SYNONYMS:
E1004

CREATION DATE: Oct 21 2006
REVISION DATE: Jun 12 2007


2. COMPOSITION, INFORMATION ON INGREDIENTS


COMPONENT: NON-HAZARDOUS SUBSTANCE
CAS NUMBER: Not assigned.
PERCENTAGE: >78

COMPONENT: SILICIC ACID HYDRATE
CAS NUMBER: 1343-98-2
PERCENTAGE: 5-10

COMPONENT: SILICA, AMORPHOUS, FUMED
CAS NUMBER: 112945-52-5
PERCENTAGE: 1-5

COMPONENT: METHYLATED BUTYLATED MELAMINE-FORMALDEHYDE RESIN - TRADE SECRET
CAS NUMBER: Not assigned.
PERCENTAGE: 1-2

COMPONENT: HYDROPHOBIC AMORPHOUS FUMED SILICA
CAS NUMBER: 68909-20-6
PERCENTAGE: 0.5-1.5

COMPONENT: DIBUTYLTIN OXIDE
CAS NUMBER: 818-08-6
PERCENTAGE: 0.5-1

COMPONENT: BIS(1,2,2,6,6,-PENTAMETHYL-4-PIPERIDYL)DECANEDIOATE
CAS NUMBER: 41556-26-7
PERCENTAGE: <1

COMPONENT: METHYL ALCOHOL
CAS NUMBER: 67-56-1
PERCENTAGE: <0.5


3. HAZARDS IDENTIFICATION


NFPA RATINGS (SCALE 0-4):  HEALTH=2  FIRE=1  REACTIVITY=0

EMERGENCY OVERVIEW:
PHYSICAL FORM: paste
ODOR: sweet alcohol odor
MAJOR HEALTH HAZARDS: harmful on contact with the skin, harmful if swallowed, eye irritation, allergic reactions

POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: mild irritation
LONG TERM EXPOSURE: no information on significant adverse effects
SKIN CONTACT:
SHORT TERM EXPOSURE: irritation, allergic reactions
LONG TERM EXPOSURE: no information on significant adverse effects
EYE CONTACT:
SHORT TERM EXPOSURE: irritation, eye damage
LONG TERM EXPOSURE: irritation
INGESTION:
SHORT TERM EXPOSURE: gastrointestinal irritation, nausea, digestive disorders
LONG TERM EXPOSURE: no information on significant adverse effects


4. FIRST AID MEASURES


INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention.

SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.

EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.

INGESTION: If a large amount is swallowed, get medical attention.


5. FIRE FIGHTING MEASURES


FIRE AND EXPLOSION HAZARDS: Slight fire hazard.

EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical, regular foam, water

FIRE FIGHTING: Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.

FLASH POINT: >200 F (>93.3 C)
FLAMMABILITY CLASS (OSHA): IIIB

HAZARDOUS COMBUSTION PRODUCTS:
Thermal decomposition or combustion products: aldehydes, acids, oxides of carbon, oxides of silicon


6. ACCIDENTAL RELEASE MEASURES


WATER RELEASE:
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and sewers.

OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Notify Local Emergency Planning Committee and State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).


7. HANDLING AND STORAGE


STORAGE: Store and handle in accordance with all current regulations and standards. Avoid contact with water or moisture. Store below 90 F. Store in a cool, dry place. Store in a well-ventilated area. Empty containers may contain product residue. Notify State Emergency Response Commission for storage or use at amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR 355.30). See original container for storage recommendations. Keep separated from incompatible substances.

HANDLING: Wash thoroughly after handling. Remove and launder contaminated clothing separately from other laundry before reuse. Avoid contact with eyes, skin and clothing. Avoid ingestion. When using, do not eat, drink or smoke. Subject to handling regulations: U.S. OSHA 29 CFR 1910.119.


8. EXPOSURE CONTROLS, PERSONAL PROTECTION


EXPOSURE LIMITS:
SILICIC ACID HYDRATE:
SILICON DIOXIDE, AMORPHOUS (SILICA, AMORPHOUS):
20 mppcf OSHA TWA (
<1% crystalline silica)>OSHA TWA (
<1% crystalline silica) (80 mg/m3 divided by %SiO2)>6 mg/m3 NIOSH recommended TWA 10 hour(s)

SILICA, AMORPHOUS, FUMED:
SILICON DIOXIDE, AMORPHOUS (SILICA, AMORPHOUS):
20 mppcf OSHA TWA (
<1% crystalline silica)>OSHA TWA (
<1% crystalline silica) (80 mg/m3 divided by %SiO2)>6 mg/m3 NIOSH recommended TWA 10 hour(s)

HYDROPHOBIC AMORPHOUS FUMED SILICA:
SILICON DIOXIDE, AMORPHOUS (SILICA, AMORPHOUS):
20 mppcf OSHA TWA (
<1% crystalline silica)>OSHA TWA (
<1% crystalline silica) (80 mg/m3 divided by %SiO2)>6 mg/m3 NIOSH recommended TWA 10 hour(s)

DIBUTYLTIN OXIDE:
TIN, ORGANIC COMPOUNDS (as Sn):
0.1 mg/m3 OSHA TWA
0.1 mg/m3 ACGIH TWA (cutaneous absorption danger)
0.2 mg/m3 ACGIH STEL (cutaneous absorption danger)
0.1 mg/m3 NIOSH recommended TWA 10 hour(s) (skin)

VENTILATION: Under normal conditions of use, no special ventilation equipment is needed. Ensure compliance with applicable exposure limits.

EYE PROTECTION: Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.

CLOTHING: Wear appropriate chemical resistant clothing.

GLOVES: Wear appropriate chemical resistant gloves.

RESPIRATOR: No respirator is required under normal conditions of use. Under conditions of frequent use or heavy exposure, respiratory protection may be needed.


9. PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL STATE: liquid
APPEARANCE: clear
PHYSICAL FORM: paste
ODOR: sweet alcohol odor
BOILING POINT: Not available
FREEZING POINT: Not available
VAPOR PRESSURE: Not available
VAPOR DENSITY (air=1): not volatile
SPECIFIC GRAVITY (water=1): 1.1
WATER SOLUBILITY: insoluble
PH: Not available
VOLATILITY: Not available
VOLATILITY BY WEIGHT: <1.5%
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not available
VOC: 17 g/L
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not available


10. STABILITY AND REACTIVITY


REACTIVITY: Stable at normal temperatures and pressure.

CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.

INCOMPATIBILITIES: oxidizing materials

HAZARDOUS DECOMPOSITION:
Decomposition products on contact with water or moisture: methanol
Thermal decomposition or combustion products: aldehydes, acids, oxides of carbon, oxides of silicon

POLYMERIZATION: Will not polymerize.


11. TOXICOLOGICAL INFORMATION


SILICIC ACID HYDRATE:
TOXICITY DATA: >2 mg/l inhalation-rat LC50; >2000 mg/kg skin-rabbit LD50; >31600 mg/kg oral-rat LD50
CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal Inadequate Evidence, Group 3
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: respiratory disorders

SILICA, AMORPHOUS, FUMED:
TOXICITY DATA: 3160 mg/kg oral-rat LD50
CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal Inadequate Evidence, Group 3
ACUTE TOXICITY LEVEL:
Moderately Toxic: ingestion
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: respiratory disorders

HYDROPHOBIC AMORPHOUS FUMED SILICA:
TOXICITY DATA: >5000 mg/kg oral-rat LD50
CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal Inadequate Evidence, Group 3 (Amorphous silica)
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: eye disorders, respiratory disorders, skin disorders and allergies

DIBUTYLTIN OXIDE:
IRRITATION DATA: 500 mg/24 hour(s) skin-rabbit mild; 100 mg eyes-rabbit severe
TOXICITY DATA: 44900 ug/kg oral-rat LD50
CARCINOGEN STATUS: ACGIH: A4 -Not Classifiable as a Human Carcinogen (Organic compounds)
LOCAL EFFECTS:
Irritant: inhalation, skin, eye
ACUTE TOXICITY LEVEL:
Highly Toxic: ingestion
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: central nervous system disorders, kidney disorders, liver disorders, skin disorders
REPRODUCTIVE EFFECTS DATA: Available.

BIS(1,2,2,6,6,-PENTAMETHYL-4-PIPERIDYL)DECANEDIOATE:
TOXICITY DATA: 3.1 g/kg oral-rat LD50
ACUTE TOXICITY LEVEL:
Moderately Toxic: ingestion
TARGET ORGANS: immune system (sensitizer)


12. ECOLOGICAL INFORMATION


Not available


13. DISPOSAL CONSIDERATIONS


Dispose in accordance with all applicable regulations.


14. TRANSPORT INFORMATION


U.S. DEPARTMENT OF TRANSPORTATION: No classification assigned.

CANADIAN TRANSPORTATION OF DANGEROUS GOODS: No classification assigned.


15. REGULATORY INFORMATION


U.S. REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4):
Formaldehyde: 100 LBS RQ
METHYL ALCOHOL (METHANOL): 5000 LBS RQ

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30):
Formaldehyde: 500 LBS TPQ

SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40):
Formaldehyde: 100 LBS RQ

SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: Yes
CHRONIC: Yes
FIRE: No
REACTIVE: No
SUDDEN RELEASE: No

SARA TITLE III SECTION 313 (40 CFR 372.65):
Formaldehyde

OSHA PROCESS SAFETY (29CFR1910.119):
Formaldehyde: 1000 LBS TQ

STATE REGULATIONS:
California Proposition 65:
Known to the state of California to cause the following:
Formaldehyde
Cancer (Jan 01, 1988)

CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: Not determined.

NATIONAL INVENTORY STATUS:
U.S. INVENTORY (TSCA): One or more components of this product are not listed.

TSCA 12(b) EXPORT NOTIFICATION: Not listed.

CANADA INVENTORY (DSL/NDSL): Not determined.


16. OTHER INFORMATION


©Copyright 1984-2007 MDL Information Systems, Inc. All rights reserved.

SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.