
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
|
Elmer's Products, Inc. |
Emergency Phone Number: |
|
1 Easton Oval |
Poison Control Center |
|
Columbus, OH 43219 |
1-888-516-2502 |
For additional product information, access
our website at www.elmers.com or call 1-888-435-6377. To place an order, call
1-800-848-9400.
SUBSTANCE:
ELMER'S PLASTIC CEMENT
TRADE NAMES/SYNONYMS:
E1004
CREATION DATE: Oct 21 2006
REVISION DATE: Jun 12 2007
2. COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENT:
NON-HAZARDOUS SUBSTANCE
CAS NUMBER: Not assigned.
PERCENTAGE: >78
COMPONENT: SILICIC ACID HYDRATE
CAS NUMBER: 1343-98-2
PERCENTAGE: 5-10
COMPONENT: SILICA, AMORPHOUS,
FUMED
CAS NUMBER: 112945-52-5
PERCENTAGE: 1-5
COMPONENT: METHYLATED BUTYLATED
MELAMINE-FORMALDEHYDE RESIN - TRADE SECRET
CAS NUMBER: Not assigned.
PERCENTAGE: 1-2
COMPONENT: HYDROPHOBIC AMORPHOUS
FUMED SILICA
CAS NUMBER: 68909-20-6
PERCENTAGE: 0.5-1.5
COMPONENT: DIBUTYLTIN OXIDE
CAS NUMBER: 818-08-6
PERCENTAGE: 0.5-1
COMPONENT:
BIS(1,2,2,6,6,-PENTAMETHYL-4-PIPERIDYL)DECANEDIOATE
CAS NUMBER: 41556-26-7
PERCENTAGE: <1
COMPONENT: METHYL ALCOHOL
CAS NUMBER: 67-56-1
PERCENTAGE: <0.5
3. HAZARDS IDENTIFICATION
NFPA RATINGS
(SCALE 0-4): HEALTH=2 FIRE=1 REACTIVITY=0
EMERGENCY OVERVIEW:
PHYSICAL FORM: paste
ODOR: sweet alcohol odor
MAJOR HEALTH HAZARDS: harmful on
contact with the skin, harmful if swallowed, eye irritation, allergic reactions
POTENTIAL HEALTH EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: mild
irritation
LONG TERM EXPOSURE: no information
on significant adverse effects
SKIN CONTACT:
SHORT TERM EXPOSURE: irritation,
allergic reactions
LONG TERM EXPOSURE: no information
on significant adverse effects
EYE CONTACT:
SHORT TERM EXPOSURE: irritation,
eye damage
LONG TERM EXPOSURE: irritation
INGESTION:
SHORT TERM EXPOSURE: gastrointestinal
irritation, nausea, digestive disorders
LONG TERM EXPOSURE: no information
on significant adverse effects
4. FIRST AID MEASURES
INHALATION:
If adverse effects occur, remove to uncontaminated area. Give artificial
respiration if not breathing. Get immediate medical attention.
SKIN CONTACT: Wash skin with soap
and water for at least 15 minutes while removing contaminated clothing and
shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated
clothing and shoes before reuse.
EYE CONTACT: Flush eyes with
plenty of water for at least 15 minutes. Then get immediate medical attention.
INGESTION: If a large amount is
swallowed, get medical attention.
5. FIRE FIGHTING MEASURES
FIRE AND
EXPLOSION HAZARDS: Slight fire hazard.
EXTINGUISHING MEDIA: carbon
dioxide, regular dry chemical, regular foam, water
FIRE FIGHTING: Move container from
fire area if it can be done without risk. Avoid inhalation of material or
combustion by-products. Stay upwind and keep out of low areas.
FLASH POINT: >200 F (>93.3
C)
FLAMMABILITY CLASS (OSHA): IIIB
HAZARDOUS COMBUSTION PRODUCTS:
Thermal decomposition or combustion products: aldehydes, acids, oxides of
carbon, oxides of silicon
6. ACCIDENTAL RELEASE MEASURES
WATER
RELEASE:
Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65). Keep out of water supplies and sewers.
OCCUPATIONAL RELEASE:
Stop leak if possible without personal risk. Small spills: Absorb with sand or
other non-combustible material. Collect spilled material in appropriate
container for disposal. Notify Local Emergency Planning Committee and State
Emergency Response Commission for release greater than or equal to RQ (U.S.
SARA Section 304). If release occurs in the U.S. and is reportable under CERCLA
Section 103, notify the National Response Center at (800)424-8802 (USA) or
(202)426-2675 (USA).
7. HANDLING AND STORAGE
STORAGE:
Store and handle in accordance with all current regulations and standards.
Avoid contact with water or moisture. Store below 90 F. Store in a cool, dry
place. Store in a well-ventilated area. Empty containers may contain product
residue. Notify State Emergency Response Commission for storage or use at
amounts greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA
Section 303 requires facilities storing a material with a TPQ to participate in
local emergency response planning (U.S. EPA 40 CFR 355.30). See original
container for storage recommendations. Keep separated from incompatible
substances.
HANDLING: Wash thoroughly after
handling. Remove and launder contaminated clothing separately from other
laundry before reuse. Avoid contact with eyes, skin and clothing. Avoid
ingestion. When using, do not eat, drink or smoke. Subject to handling
regulations: U.S. OSHA 29 CFR 1910.119.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE
LIMITS:
SILICIC ACID HYDRATE:
SILICON DIOXIDE, AMORPHOUS (SILICA,
AMORPHOUS):
20 mppcf OSHA TWA (
<1% crystalline silica)>OSHA TWA (
<1% crystalline silica) (80 mg/m3 divided by %SiO2)>6 mg/m3 NIOSH recommended
TWA 10 hour(s)
SILICA, AMORPHOUS, FUMED:
SILICON DIOXIDE, AMORPHOUS (SILICA,
AMORPHOUS):
20 mppcf OSHA TWA (
<1% crystalline silica)>OSHA TWA (
<1% crystalline silica) (80 mg/m3 divided by %SiO2)>6 mg/m3 NIOSH recommended
TWA 10 hour(s)
HYDROPHOBIC AMORPHOUS FUMED SILICA:
SILICON DIOXIDE, AMORPHOUS (SILICA,
AMORPHOUS):
20 mppcf OSHA TWA (
<1% crystalline silica)>OSHA TWA (
<1% crystalline silica) (80 mg/m3 divided by %SiO2)>6 mg/m3 NIOSH recommended
TWA 10 hour(s)
DIBUTYLTIN OXIDE:
TIN, ORGANIC COMPOUNDS (as Sn):
0.1 mg/m3 OSHA TWA
0.1 mg/m3 ACGIH TWA (cutaneous absorption danger)
0.2 mg/m3 ACGIH STEL (cutaneous absorption danger)
0.1 mg/m3 NIOSH recommended TWA 10 hour(s) (skin)
VENTILATION: Under normal
conditions of use, no special ventilation equipment is needed. Ensure
compliance with applicable exposure limits.
EYE PROTECTION: Wear splash
resistant safety goggles with a faceshield. Provide an emergency eye wash fountain
and quick drench shower in the immediate work area.
CLOTHING: Wear appropriate
chemical resistant clothing.
GLOVES: Wear appropriate chemical
resistant gloves.
RESPIRATOR: No respirator is
required under normal conditions of use. Under conditions of frequent use or
heavy exposure, respiratory protection may be needed.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL
STATE: liquid
APPEARANCE: clear
PHYSICAL FORM: paste
ODOR: sweet alcohol odor
BOILING POINT: Not available
FREEZING POINT: Not available
VAPOR PRESSURE: Not available
VAPOR DENSITY (air=1): not
volatile
SPECIFIC GRAVITY (water=1): 1.1
WATER SOLUBILITY: insoluble
PH: Not available
VOLATILITY: Not available
VOLATILITY BY WEIGHT: <1.5%
ODOR THRESHOLD: Not available
EVAPORATION RATE: Not available
VOC: 17 g/L
COEFFICIENT OF WATER/OIL DISTRIBUTION:
Not available
10. STABILITY AND REACTIVITY
REACTIVITY:
Stable at normal temperatures and pressure.
CONDITIONS TO AVOID: Avoid heat,
flames, sparks and other sources of ignition. Avoid contact with incompatible
materials.
INCOMPATIBILITIES: oxidizing
materials
HAZARDOUS DECOMPOSITION:
Decomposition products on contact with water or moisture: methanol
Thermal decomposition or combustion products: aldehydes, acids, oxides of
carbon, oxides of silicon
POLYMERIZATION: Will not
polymerize.
11. TOXICOLOGICAL INFORMATION
SILICIC
ACID HYDRATE:
TOXICITY DATA: >2 mg/l
inhalation-rat LC50; >2000 mg/kg skin-rabbit LD50; >31600 mg/kg oral-rat
LD50
CARCINOGEN STATUS: IARC: Human
Inadequate Evidence, Animal Inadequate Evidence, Group 3
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
respiratory disorders
SILICA, AMORPHOUS, FUMED:
TOXICITY DATA: 3160 mg/kg oral-rat
LD50
CARCINOGEN STATUS: IARC: Human
Inadequate Evidence, Animal Inadequate Evidence, Group 3
ACUTE TOXICITY LEVEL:
Moderately Toxic: ingestion
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
respiratory disorders
HYDROPHOBIC AMORPHOUS FUMED SILICA:
TOXICITY DATA: >5000 mg/kg
oral-rat LD50
CARCINOGEN STATUS: IARC: Human
Inadequate Evidence, Animal Inadequate Evidence, Group 3 (Amorphous silica)
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
eye disorders, respiratory disorders, skin disorders and allergies
DIBUTYLTIN OXIDE:
IRRITATION DATA: 500 mg/24 hour(s)
skin-rabbit mild; 100 mg eyes-rabbit severe
TOXICITY DATA: 44900 ug/kg oral-rat
LD50
CARCINOGEN STATUS: ACGIH: A4 -Not
Classifiable as a Human Carcinogen (Organic compounds)
LOCAL EFFECTS:
Irritant: inhalation, skin, eye
ACUTE TOXICITY LEVEL:
Highly Toxic: ingestion
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
central nervous system disorders, kidney disorders, liver disorders, skin
disorders
REPRODUCTIVE EFFECTS DATA:
Available.
BIS(1,2,2,6,6,-PENTAMETHYL-4-PIPERIDYL)DECANEDIOATE:
TOXICITY DATA: 3.1 g/kg oral-rat
LD50
ACUTE TOXICITY LEVEL:
Moderately Toxic: ingestion
TARGET ORGANS: immune system
(sensitizer)
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Dispose in accordance with all applicable regulations.
14. TRANSPORT INFORMATION
U.S.
DEPARTMENT OF TRANSPORTATION: No classification assigned.
CANADIAN TRANSPORTATION OF DANGEROUS GOODS:
No classification assigned.
15. REGULATORY INFORMATION
U.S.
REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES
(40 CFR 302.4):
Formaldehyde: 100 LBS RQ
METHYL ALCOHOL (METHANOL):
5000 LBS RQ
SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30):
Formaldehyde:
500 LBS TPQ
SARA TITLE III SECTION 304 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.40):
Formaldehyde: 100 LBS RQ
SARA TITLE III SARA SECTIONS 311/312
HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: Yes
CHRONIC: Yes
FIRE: No
REACTIVE: No
SUDDEN RELEASE: No
SARA TITLE III SECTION 313 (40 CFR 372.65):
Formaldehyde
OSHA PROCESS SAFETY (29CFR1910.119):
Formaldehyde:
1000 LBS TQ
STATE REGULATIONS:
California Proposition 65:
Known to the state of California to cause the following:
Formaldehyde
Cancer (Jan 01, 1988)
CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: Not
determined.
NATIONAL INVENTORY STATUS:
U.S. INVENTORY (TSCA): One or more
components of this product are not listed.
TSCA 12(b) EXPORT NOTIFICATION:
Not listed.
CANADA INVENTORY (DSL/NDSL): Not
determined.
16. OTHER INFORMATION
©Copyright 1984-2007 MDL Information Systems, Inc. All rights reserved.
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.