DESCRIPTION: PROBOND ADH. CAULK KITCHEN & BATH WHITE PRODUCT TYPE: MODIFIED SILICONE APPLICATION: P-9503
MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1000 Kingsmill Parkway Poison Control Center Columbus, OH 43229 1-800-228-5635 ext 22 For additional health, safety or regulatory information, call 614-225-7695. Call 1-800-848-9400 to place an order or request additional MSDSs.
The ingredients listed below have been associated with one or more immediate and/or delayed(*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS. % by weight 1317-65-3 *Limestone 50-70 1760-24-3 *N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1-5 2768-02-7 *Vinyltrimethoxysilane 1-5 13463-67-7 *Titanium Dioxide 5-10 Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha.', 30-50 .alpha.''-1,2,3-propanetriyltris[.omega.-[3-(dimeth- oxymethylsilyl)propoxy]-, polymer with .alpha.-[3- (dimethoxymethylsilyl)propyl]-.omega.-[3-(dimethoxy
Appearance White paste Odor Mild CAUTION! Will burn. May be harmful if swallowed. May be harmful if inhaled. May cause irritation of nose, throat and lungs. May be harmful if absorbed through skin. Causes skin irritation. Causes eye irritation. Irritation may be severe.
HEALTH = 2 (moderate) FLAMMABILITY = 1 (slight) REACTIVITY = 0 (minimal) CHRONIC = *
INGESTION: May be harmful if swallowed. If accidentally swallowed, burns or irritation to mucous membranes, esophagus or GI tract can result. Can cause central nervous system depression. INHALATION: May be harmful if inhaled. Vapor may cause irritation of nose, throat and lungs. SKIN May be harmful if absorbed through skin. Causes irritation. Irritation may be severe. EYES: Causes irritation. Irritation may be severe. N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3 Reacts with water in stomach to produce methanol which may cause blindness and central nervous system depression. Vinyltrimethoxysilane 2768-02-7 Reacts with water in stomach to produce methanol which may cause blindness and central nervous system depression.
Limestone 1317-65-3 Can cause lung damage. Pre-existing respiratory disorders may be aggravated by exposure. -- See Footnote C. N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3 May cause allergic skin reaction. -- See Footnote C. Vinyltrimethoxysilane 2768-02-7 Possible birth defect hazard. May cause birth defects based on animal data. Can cause liver damage. Can cause kidney damage. -- See Footnote C. Titanium Dioxide 13463-67-7 Inhalation at approximately 50 times the level permitted in an occupational environment caused a slight increase in lung tumor incidence in laboratory animals. No tumors were found at lower exposure levels. This material is not listed by NTP, classified by IARC nor regulated by OSHA as a carcinogen. Can cause lung fibrosis. Pre-existing respiratory disorders may be aggravated by exposure. Footnote C: As of the date of issuance of this document, this material has not been listed by NTP, classified by IARC nor regulated by OSHA as a carcinogen.
INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Call a physician. SKIN: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing and shoes before reuse. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held apart during irrigation to insure water contact with entire surface of eyes and lids. Call a physician.
Autoignition Temperature Not established Upper/Lower Flammable Limits Not established Up/Lower Explosive Limits, % by Vol Not established Flash Point >200°F Will burn. In case of fire, use dry chemical, foam or CO2. Water may be ineffective, but should be used to keep fire-exposed containers cool.
Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water.
Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). INHALATION: Avoid breathing vapor. Use with adequate ventilation. SKIN: Avoid contact with skin and clothing. EYES: Avoid contact with eyes.
Store at room temperature. Store in a cool, well-ventilated area. Keep containers tightly closed.
ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and remote control in combination with appropriate use of personal protective equipment and prudent work practices. These techniques may not necessarily address all issues pertaining to your operations. We, therefore, recommend that you consult with experts of your choice to determine whether or not your programs are adequate. If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria.
Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA laws and regulations or other applicable standards or guidelines, including ANSI standards regarding respiratory protection. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin contact.
Limestone 1317-65-3 ACGIH TLV: 10 mg/m³ TWA, inhalable particulate OSHA PEL: 5 mg/m³ TWA, respirable particulates; 15 mg/m³ TWA total dust N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3 ACGIH TLV: NONE ESTABLISHED OSHA PEL: NONE ESTABLISHED Vinyltrimethoxysilane 2768-02-7 ACGIH TLV: NONE ESTABLISHED OSHA PEL: NONE ESTABLISHED Titanium Dioxide 13463-67-7 ACGIH TLV: 10 mg/m³ TWA OSHA PEL: 15 mg/m³ TWA, total dust REMANDED PEL: 10 mg/m³ TWA, Total dust OSHA 1989 PEL remanded, but in effect in some states Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha.', .alpha.''-1,2,3-propanetriyltris[.omega.-[3-(dimeth- oxymethylsilyl)propoxy]-, polymer with .alpha.-[3- (dimethoxymethylsilyl)propyl]-.omega.-[3-(dimethoxy ACGIH TLV: NONE ESTABLISHED OSHA PEL: NONE ESTABLISHED
Percent Volatiles 1 pH @ 25 C Not applicable Specific Gravity 1.5 Appearance White paste Autoignition Temperature Not established Boiling Point Not established Vapor Density (Air=1) Not established Vapor Pressure, mm Hg @ 20 C Not established Evaporation Rate (Butyl Acetate=1) Not established Upper/Lower Flammable Limits Not established Up/Lower Explosive Limits, % by Vol Not established Flash Point >200°F Freezing Point Not applicable Melting point Not established Odor Mild Solubility in Water Slightly soluble
Normally stable as defined in NFPA 704-12(4-3.1).
Transition metal compounds.
Oxides of carbon and nitrogen by thermal decomposition.
Will not occur.
None known to company.
See Section 3 Hazards Identification information. Limestone 1317-65-3 LC50: Not available LD50: Not available N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3 LC50: Not available LD50: orl-rat=7460 mg/kg (RTECS) Vinyltrimethoxysilane 2768-02-7 LC50: Not available LD50: orl-rat=11300 mg/kg; skn-rbt=3540 mg/kg (RTECS) Titanium Dioxide 13463-67-7 LC50: Not available LD50: Not available Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha.', .alpha.''-1,2,3-propanetriyltris[.omega.-[3-(dimeth- oxymethylsilyl)propoxy]-, polymer with .alpha.-[3- (dimethoxymethylsilyl)propyl]-.omega.-[3-(dimethoxy LC50: Not available LD50: Not available
Dispose of according to local, state/provincial, and federal requirements.
The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Non-Regulated.
This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard.
Immediate health hazard Delayed health hazard
This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313.
All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. CLASS D, DIV 1B CLASS D, DIV 2A, 2B
All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements.
This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required.
CL (Cautionary Labeling): Products bearing the CL (Cautionary Labeling) Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified to be properly labeled in a program of toxicological evaluation by a medical expert. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695.
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients.
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.
CUR ISSUE 14-SEP-01 PREVIOUS ISSUE: 28-SEP-00