DESCRIPTION: PROBOND ADH. CAULK KITCHEN & BATH WHITE
PRODUCT TYPE: MODIFIED SILICONE
APPLICATION: P-9503
MSDS Prepared by:
Elmer's Products, Inc. Emergency Phone Number
1000 Kingsmill Parkway Poison Control Center
Columbus, OH 43229 1-800-228-5635 ext 22
For additional health, safety or regulatory information, call 614-225-7695.
Call 1-800-848-9400 to place an order or request additional MSDSs.
The ingredients listed below have been associated with one or more
immediate and/or delayed(*) health hazards. Risk of damage and effects
depends upon duration and level of exposure. BEFORE USING, HANDLING, OR
EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.
% by weight
1317-65-3 *Limestone 50-70
1760-24-3 *N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1-5
2768-02-7 *Vinyltrimethoxysilane 1-5
13463-67-7 *Titanium Dioxide 5-10
Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha.', 30-50
.alpha.''-1,2,3-propanetriyltris[.omega.-[3-(dimeth-
oxymethylsilyl)propoxy]-, polymer with .alpha.-[3-
(dimethoxymethylsilyl)propyl]-.omega.-[3-(dimethoxy
Appearance White paste
Odor Mild
CAUTION!
Will burn.
May be harmful if swallowed.
May be harmful if inhaled. May cause irritation of nose, throat and
lungs.
May be harmful if absorbed through skin.
Causes skin irritation.
Causes eye irritation.
Irritation may be severe.
HEALTH = 2 (moderate)
FLAMMABILITY = 1 (slight)
REACTIVITY = 0 (minimal)
CHRONIC = *
INGESTION: May be harmful if swallowed.
If accidentally swallowed, burns or irritation to
mucous membranes, esophagus or GI tract can result.
Can cause central nervous system depression.
INHALATION: May be harmful if inhaled. Vapor may cause irritation
of nose, throat and lungs.
SKIN May be harmful if absorbed through skin. Causes
irritation.
Irritation may be severe.
EYES: Causes irritation.
Irritation may be severe.
N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3
Reacts with water in stomach to produce methanol which may cause
blindness and central nervous system depression.
Vinyltrimethoxysilane 2768-02-7
Reacts with water in stomach to produce methanol which may cause
blindness and central nervous system depression.
Limestone 1317-65-3
Can cause lung damage. Pre-existing respiratory disorders may be
aggravated by exposure.
-- See Footnote C.
N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3
May cause allergic skin reaction.
-- See Footnote C.
Vinyltrimethoxysilane 2768-02-7
Possible birth defect hazard. May cause birth defects based on
animal data.
Can cause liver damage.
Can cause kidney damage.
-- See Footnote C.
Titanium Dioxide 13463-67-7
Inhalation at approximately 50 times the level permitted in an
occupational environment caused a slight increase in lung tumor
incidence in laboratory animals. No tumors were found at lower
exposure levels. This material is not listed by NTP, classified by
IARC nor regulated by OSHA as a carcinogen.
Can cause lung fibrosis. Pre-existing respiratory disorders may
be aggravated by exposure.
Footnote C: As of the date of issuance of this document, this
material has not been listed by NTP, classified by IARC nor regulated
by OSHA as a carcinogen.
INGESTION: If accidentally swallowed, dilute by drinking large
quantities of water. Immediately contact poison control
center or hospital emergency room for any other
additional treatment directions.
INHALATION: If inhaled, remove to fresh air. If not breathing,
give artificial respiration, preferably mouth-to-mouth.
Call a physician.
SKIN: Immediately flush with plenty of water for at least
15 minutes while removing contaminated clothing and
shoes. Wash clothing and shoes before reuse.
EYES: Immediately flush eyes with plenty of water for at
least 15 minutes. Eyelids should be held apart during
irrigation to insure water contact with entire surface of
eyes and lids. Call a physician.
Autoignition Temperature Not established
Upper/Lower Flammable Limits Not established
Up/Lower Explosive Limits, % by Vol Not established
Flash Point >200°F
Will burn.
In case of fire, use dry chemical, foam or CO2. Water may
be ineffective, but should be used to keep fire-exposed containers
cool.
Sweep (scoop) up and remove to a chemical disposal area. Prevent
entry into natural bodies of water.
Handle in accordance with good industrial hygiene and safety
practices. These practices include avoiding unnecessary exposure and
removal of the material from eyes, skin and clothing.
Wash thoroughly after handling. Always use appropriate Personal
Protective Equipment (PPE).
INHALATION: Avoid breathing vapor. Use with adequate
ventilation.
SKIN: Avoid contact with skin and clothing.
EYES: Avoid contact with eyes.
Store at room temperature.
Store in a cool, well-ventilated area.
Keep containers tightly closed.
ENGINEERING CONTROLS: The following exposure control techniques may
be used to effectively minimize employee exposure: local exhaust
ventilation, enclosed system design, process isolation and remote
control in combination with appropriate use of personal protective
equipment and prudent work practices. These techniques may not
necessarily address all issues pertaining to your operations. We,
therefore, recommend that you consult with experts of your choice to
determine whether or not your programs are adequate.
If airborne contaminants are generated when the material is heated or
handled, sufficient ventilation in volume and air flow patterns should
be provided to keep air contaminant concentration levels below
acceptable criteria.
Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA
approved respiratory protection equipment. Respirators should be
selected based on the form and concentration of contaminants in air
in accordance with OSHA laws and regulations or other applicable
standards or guidelines, including ANSI standards regarding
respiratory protection. Use goggles if contact is likely. Wear
impervious gloves as required to prevent skin contact.
Limestone 1317-65-3
ACGIH TLV: 10 mg/m³ TWA, inhalable particulate
OSHA PEL: 5 mg/m³ TWA, respirable particulates; 15 mg/m³ TWA
total dust
N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
Vinyltrimethoxysilane 2768-02-7
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
Titanium Dioxide 13463-67-7
ACGIH TLV: 10 mg/m³ TWA
OSHA PEL: 15 mg/m³ TWA, total dust
REMANDED PEL: 10 mg/m³ TWA, Total dust
OSHA 1989 PEL remanded, but in effect in some states
Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha.',
.alpha.''-1,2,3-propanetriyltris[.omega.-[3-(dimeth-
oxymethylsilyl)propoxy]-, polymer with .alpha.-[3-
(dimethoxymethylsilyl)propyl]-.omega.-[3-(dimethoxy
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
Percent Volatiles 1
pH @ 25 C Not applicable
Specific Gravity 1.5
Appearance White paste
Autoignition Temperature Not established
Boiling Point Not established
Vapor Density (Air=1) Not established
Vapor Pressure, mm Hg @ 20 C Not established
Evaporation Rate (Butyl Acetate=1) Not established
Upper/Lower Flammable Limits Not established
Up/Lower Explosive Limits, % by Vol Not established
Flash Point >200°F
Freezing Point Not applicable
Melting point Not established
Odor Mild
Solubility in Water Slightly soluble
Normally stable as defined in NFPA 704-12(4-3.1).
Transition metal compounds.
Oxides of carbon and nitrogen by thermal decomposition.
Will not occur.
None known to company.
See Section 3 Hazards Identification information.
Limestone 1317-65-3
LC50: Not available
LD50: Not available
N-(2-Aminoethyl)-3-Aminopropyltrimethoxysilane 1760-24-3
LC50: Not available
LD50: orl-rat=7460 mg/kg (RTECS)
Vinyltrimethoxysilane 2768-02-7
LC50: Not available
LD50: orl-rat=11300 mg/kg; skn-rbt=3540 mg/kg (RTECS)
Titanium Dioxide 13463-67-7
LC50: Not available
LD50: Not available
Poly[oxy(methyl-1,2-ethanediyl)], .alpha., .alpha.',
.alpha.''-1,2,3-propanetriyltris[.omega.-[3-(dimeth-
oxymethylsilyl)propoxy]-, polymer with .alpha.-[3-
(dimethoxymethylsilyl)propyl]-.omega.-[3-(dimethoxy
LC50: Not available
LD50: Not available
Not determined.
Dispose of according to local, state/provincial, and federal
requirements.
The data provided in this section is for information only and may not
be specific to your package size. You will need to apply the
appropriate regulations to properly classify your shipment for
transportation.
Non-Regulated.
Not determined.
This material is a "health hazard" and/or a "physical hazard" as
determined when reviewed according to the requirements of the
Occupational Safety and Health Administration 29 CFR Part 1910.1200
"Hazard Communication" Standard.
Immediate health hazard
Delayed health hazard
This product contains the following toxic chemical(s) subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
Notification Requirement of 40 CFR Part 372.
None required per SARA TITLE III SECTION 313.
All reportable chemical substances are listed on the TSCA Inventory.
We rely on certifications of compliance from our suppliers for
chemical substances not manufactured by us.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all the information required by the CPR.
CLASS D, DIV 1B
CLASS D, DIV 2A, 2B
All reportable chemical substances are listed on the Domestic
Substances List (DSL) or otherwise comply with CEPA new substance
notification requirements.
This product contains the following chemical(s) subject to the
reporting requirements of the Canadian Environmental Protection Act
(CEPA) subsection 16(1), National Pollutant Release Inventory.
None required.
CL (Cautionary Labeling): Products bearing the CL (Cautionary
Labeling) Seal of The Art & Creative Materials Institute, Inc. (ACMI)
are certified to be properly labeled in a program of toxicological
evaluation by a medical expert. This program is reviewed by ACMI's
Toxicological Advisory Board. These products are certified by ACMI
to be labeled in accordance with the chronic hazard labeling
standard, ASTM D-4236 and Federal Law, P.L. 100-695.
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information
contained on these sheets be made available to your workers. Educate and
train your workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly. Consult with appropriate experts
to guard against hazards associated with use of this product and its
ingredients.
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind
shall be greater in amount than the purchase price of the quantity of
product in respect of which damages are claimed. In no event shall Seller
be liable for incidental or consequential damages, whether Buyer's claim is
based on contract, breach of warranty, negligence or otherwise.
CUR ISSUE 14-SEP-01
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