Material
Safety Data Sheet
1. Chemical Product and Company
Identification
DESCRIPTION: PROBOND PROFESSIONAL CONTACT CEMENT
PRODUCT TYPE: SYNTHETIC RUBBER SOLUTION
APPLICATION: E531, 60532
·
Manufacturer/Supplier
Information
MSDS Prepared by:
Elmer's Products, Inc. Emergency Phone Number
1 Easton Oval Poison Control Center
Columbus, OH 43219 888-516-2502
For additional health, safety or regulatory information, call 888-435-6377.
Call 1-800-848-9400 to place an order or request additional MSDSs.
2. Composition, Information on Ingredients
The ingredients listed below have been associated with one or more
immediate and/or delayed(*) health hazards. Risk of damage and effects
depends upon duration and level of exposure. BEFORE USING, HANDLING, OR
EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.
% by weight
78-93-3 *Methyl Ethyl Ketone 10-30
109-60-4 *n-Propyl Acetate 10-30
64742-89-8 Light Aliphatic Solvent Naphtha (petroleum) 30-50
3. Hazards Identification
3.1 Emergency Overview
Appearance Yellow tan medium syrup
Odor Petroleum
WARNING!
FLAMMABLE LIQUID AND VAPOR
Causes eye irritation.
Overexposure may cause central nervous system depression. May
cause irritation of nose, throat and lungs if allowed to become
airborne.
·
HMIS Rating
HEALTH = 2 (moderate)
FLAMMABILITY = 3 (serious)
REACTIVITY = 0 (minimal)
CHRONIC = *
3.2 Potential Health Effects
·
Immediate Hazards
INGESTION: No hazards known to company.
INHALATION: Not expected to be harmful under normal conditions of
use. However, overexposure may cause central nervous
system depression. Also, if allowed to become airborne,
may cause irritation of nose, throat and lungs.
SKIN: May cause irritation on prolonged or repeated contact.
EYES: Causes irritation.
Methyl Ethyl Ketone 78-93-3
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting, unconsciousness and
asphyxiation. Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and
nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may lead to addiction and may
be harmful or fatal.
n-Propyl Acetate 109-60-4
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting, unconsciousness and
even asphyxiation.
Light Aliphatic Solvent Naphtha (petroleum) 64742-89-8
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting, unconsciousness and
even asphyxiation.
·
Delayed Hazards
Methyl Ethyl Ketone 78-93-3
Suspect reproductive hazard. May cause reproductive disorders
based on animal data.
Methyl ethyl ketone may potentiate (shorten the time of onset)
peripheral neuropathy caused by methyl n-butyl ketone or n-hexane.
Methyl ethyl ketone by itself has not been shown to cause peripheral
neuropathy.
-- See Footnote C.
n-Propyl Acetate 109-60-4
May cause liver damage based on animal data.
-- See Footnote C.
Footnote C: As of the date of issuance of this document, this
material has not been listed by NTP, classified by IARC nor regulated
by OSHA as a carcinogen.
4. First Aid Measures
INGESTION: If accidentally swallowed, dilute by drinking large
quantities of water. Immediately contact poison control
center or hospital emergency room for any other
additional treatment directions.
INHALATION: Remove to fresh air.
SKIN: In case of irritation, flush with water.
EYES: Immediately flush eyes with plenty of water for at
least 15 minutes. Eyelids should be held apart during
irrigation to insure water contact with entire surface of
eyes and lids. Call a physician.
5. Fire Fighting Measures
Autoignition Temperature Not available
Upper/Lower Flammable Limits Not available
Up/Lower Explosive Limits, % by Vol 10/0.9
Flash Point > -7 deg C
FLAMMABLE.
Keep liquid and vapor away from heat, sparks, flame and other ignition
sources including, but not limited to, pilot lights, heaters,
cigarettes, electric motors and static discharge. Vapor is heavier
than air and may settle in low places or travel outward to a source of
ignition and flashback.
In case of fire, use water spray, dry chemical, foam or CO2. Use
water to keep fire-exposed containers cool.
6. Accidental Release Measures
Eliminate all ignition sources. Sweep (scoop) up and remove to a
chemical disposal area. Prevent entry into natural bodies of water.
7. Handling and Storage
7.1 Handling
Handle in accordance with good industrial hygiene and safety
practices. These practices include avoiding unnecessary exposure and
removal of the material from eyes, skin and clothing.
Wash thoroughly after handling. Always use appropriate Personal
Protective Equipment (PPE).
INHALATION: Avoid prolonged or repeated breathing of vapor.
SKIN: Persons with sensitive skin should avoid prolonged,
continuous contact with skin. If irritation develops, discontinue
use.
EYES: Avoid contact with eyes.
7.2 Storage
Store in a cool, dry place.
Keep containers tightly closed.
Keep away from heat, sparks, flame and other ignition sources.
8. Exposure Controls/Personal Protection
8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure control techniques may
be used to effectively minimize employee exposure: local exhaust
ventilation, enclosed system design, process isolation and remote
control in combination with appropriate use of personal protective
equipment and prudent work practices. These techniques may not
necessarily address all issues pertaining to your operations. We,
therefore, recommend that you consult with experts of your choice to
determine whether or not your programs are adequate.
If airborne contaminants are generated when the material is heated or
handled, sufficient ventilation in volume and air flow patterns should
be provided to keep air contaminant concentration levels below
acceptable criteria.
8.2 Personal Protection
Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA
approved respiratory protection equipment. Respirators should be
selected based on the form and concentration of contaminants in air
in accordance with OSHA laws and regulations or other applicable
standards or guidelines, including ANSI standards regarding
respiratory protection.
8.3 Exposure Guidelines
Methyl Ethyl Ketone 78-93-3
ACGIH TLV: 200 ppm (590 mg/m³) TWA; 300 ppm (885 mg/m³) STEL
OSHA PEL: 200 ppm (590 mg/m³) TWA
REMANDED PEL: 200 ppm (590 mg/m³) TWA; 300 ppm (885 mg/m³) STEL
OSHA 1989 PEL remanded, but in effect in some states
n-Propyl Acetate 109-60-4
ACGIH TLV: 200 ppm (835 mg/m³) TWA; 250 ppm (1040 mg/m³) STEL
OSHA PEL: 200 ppm (840 mg/m³) TWA
REMANDED PEL: 200 ppm (840 mg/m³) TWA; 250 ppm (1050 mg/m³) STEL
OSHA 1989 PEL remanded, but in effect in some states
Light Aliphatic Solvent Naphtha (petroleum) 64742-89-8
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
9. Physical and Chemical Properties
Percent Volatiles 82
pH @ 25 C Not available
Specific Gravity 0.86
Appearance Yellow tan medium syrup
Autoignition Temperature Not available
Boiling Point 80 deg C
Vapor Density (Air=1) > 1
Vapor Pressure, mm Hg @ 20 C 45
Evaporation Rate (Butyl Acetate=1) > 1
Upper/Lower Flammable Limits Not available
Up/Lower Explosive Limits, % by Vol 10/0.9
Flash Point > -7 deg C
Freezing Point Not available
Odor Petroleum
Odor Threshold, ppm Not available
Solubility in Water Negligible
Coefficient of Water/Oil Distrib. Not applicable
10. Stability and Reactivity
Normally stable as defined in NFPA 704-12(4-3.1).
·
Incompatibilities:
Oxidizers, acids or bases.
·
Decomposition products
may include:
CO, CO2.
·
Hazardous
polymerization:
Will not occur.
·
Other Hazards:
None known to company.
11. Toxicological Information
INGESTION: Not toxic orally when tested as described in 16 CFR Part
1500.3 (c)(1) and (2).
INHALATION: Not toxic by inhalation when tested as described in 16
CFR Part 1500.3 (c)(1) and (2).
SKIN Not toxic dermally when tested as described in 16 CFR
ABSORPTION: Part 1500.3 (c)(1) and (2).
SKIN: Not a primary irritant (primary skin irritation index
less than 5.0/8.0) when tested as described in 16 CFR
Part 1500.41.
EYES: Moderately irritating when tested as described in 16 CFR
Part 1500.42.
Methyl Ethyl Ketone 78-93-3
LC50: Not available
LD50: orl-rat=6.86 ml/kg (Merck)
n-Propyl Acetate 109-60-4
LC50: Not available
LD50: orl-rat=9370 mg/kg (Merck)
Light Aliphatic Solvent Naphtha (petroleum) 64742-89-8
LC50: Not available
LD50: Not available
12. Ecological Information
Not determined.
13. Disposal Considerations
Dispose of according to local, state/provincial, and federal
requirements.
Empty container: May contain explosive vapors. DO NOT cut, puncture
or weld on or nearby.
14. Transport Information
14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information only and may not
be specific to your package size. You will need to apply the
appropriate regulations to properly classify your shipment for
transportation.
ORM-D Consumer Commodity.
14.2 Canadian Transportation of Dangerous Goods (TDG)
Not determined.
15. Regulatory Information (Selected Regulations)
15.1 U.S. Federal Regulations
·
OSHA Hazard
Communication Standard 29CFR1910.1200
This material is a "health hazard" and/or a "physical hazard" as
determined when reviewed according to the requirements of the
Occupational Safety and Health Administration 29 CFR Part 1910.1200
"Hazard Communication" Standard.
·
SARA Title III: Section
311/312
Fire hazard
Immediate health hazard
Delayed health hazard
·
SARA Title III Section
313 and 40 CFR Part 372
This product contains the following toxic chemical(s) subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
Notification Requirement of 40 CFR Part 372.
Methyl Ethyl Ketone 78-93-3 12.30%
·
TSCA Section 8(b)
Inventory
All reportable chemical substances are listed on the TSCA Inventory.
We rely on certifications of compliance from our suppliers for
chemical substances not manufactured by us.
15.2 Canadian Regulations
·
Workplace Hazardous
Materials Information System (WHMIS)
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all the information required by the CPR.
CLASS D, DIV 2B
CLASS B, DIV 2
·
Canadian Environmental
Protection Act (CEPA)
All reportable chemical substances are listed on the Domestic
Substances List (DSL) or otherwise comply with CEPA new substance
notification requirements.
·
National Pollutant
Release Inventory (NPRI)
This product contains the following chemical(s) subject to the
reporting requirements of the Canadian Environmental Protection Act
(CEPA) subsection 16(1), National Pollutant Release Inventory.
Methyl ethyl ketone 78-93-3 12.30%
16. Other Information
HL (Cautions Required): Products bearing the HL Health Label
(Cautions Required) Seal of The Art & Creative Materials Institute,
Inc. (ACMI) are certified to be properly labeled in a program of
toxicological evaluation by a medical expert. This program is
reviewed by ACMI's Toxicological Advisory Board. These products are
certified by ACMI to be labeled in accordance with the chronic hazard
labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695.
·
User's Responsibility
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information
contained on these sheets be made available to your workers. Educate and
train your workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly. Consult with appropriate experts
to guard against hazards associated with use of this product and its
ingredients.
·
Disclaimer
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind
shall be greater in amount than the purchase price of the quantity of
product in respect of which damages are claimed. In no event shall Seller
be liable for incidental or consequential damages, whether Buyer's claim is
based on contract, breach of warranty, negligence or otherwise.
CURRENT ISSUE: 23-JAN-07
PREVIOUS ISSUE: 14-APR-04