DESCRIPTION: ELMER'S HIGH PERFORMANCE SPRAY ADHESIVE PRODUCT TYPE: SOLVENT BASED ADH. AEROSOL APPLICATION: E-458
MSDS Prepared by: Elmer's Products, Inc. Emergency Phone Number 1000 Kingsmill Parkway Poison Control Center Columbus, OH 43229 1-800-228-5635 ext 22 For additional health, safety or regulatory information, call 614-985-6440 ext 14. Call 1-800-848-9400 to place an order or request additional MSDSs.
The ingredients listed below have been associated with one or more immediate and/or delayed(*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS. % by weight 50-00-0 *Formaldehyde < 0.001 67-64-1 *Acetone 10-30 74-98-6 Propane 10-30 108-88-3 *Toluene 5-10 110-54-3 *Hexane 10-30 110-82-7 *Cyclohexane 1-5 115-10-6 Dimethyl Ether 5-10
Appearance Clear amber liquid Odor Mint when wet DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR May be harmful if inhaled. May cause irritation of nose, throat and lungs. Can cause central nervous system depression. May be harmful if absorbed through skin. Causes skin irritation. Causes eye irritation.
HEALTH = 2 (moderate) FLAMMABILITY = 4 (severe) REACTIVITY = 0 (minimal) CHRONIC = *
INGESTION: Not expected to be harmful under normal conditions of use. If accidentally swallowed, burns or irritation to mucous membranes, esophagus or GI tract can result. INHALATION: May be harmful if inhaled. Liquid or vapor may cause irritation of nose, throat and lungs. Can cause central nervous system depression. SKIN: May be harmful if absorbed through skin. Causes irritation. EYES: Causes irritation. Acetone 67-64-1 Can cause central nervous system depression. Signs and symptoms may include headache, dizziness, nausea, vomiting, unconsciousness and even asphyxiation. Propane 74-98-6 This material is a simple asphyxiant. Signs and symptoms of overexposure include cyanosis, respiratory distress, headache, dizziness, drowsiness, unconsciousness and asphyxiation. Can cause central nervous system depression. Toluene 108-88-3 Can cause central nervous system depression. Signs and symptoms may include headache, dizziness, nausea, vomiting, unconsciousness and asphyxiation. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may lead to addiction and may be harmful or fatal. Hexane 110-54-3 Can cause central nervous system depression. Signs and symptoms may include headache, dizziness, nausea, vomiting, unconsciousness and even asphyxiation. Cyclohexane 110-82-7 Can cause central nervous system depression. Signs and symptoms may include headache, dizziness, nausea, vomiting, unconsciousness and even asphyxiation. Dimethyl Ether 115-10-6 Can cause central nervous system depression. Signs and symptoms may include headache, dizziness, nausea, vomiting, unconsciousness and even asphyxiation.
Formaldehyde 50-00-0 POTENTIAL CANCER HAZARD. Rats chronically exposed to 14 ppm formaldehyde contracted nasal cancers. Based on animal data and limited epidemiological evidence, NTP and IARC have listed formaldehyde as a probable human carcinogen. OSHA regulates formaldehyde as a potential human carcinogen. May cause allergic skin reaction. Some reports suggest that formaldehyde may cause respiratory sensitization, such as asthma, and that pre-existing respiratory and skin disorders may be aggravated by exposure. OSHA has identified 0.5 ppm as the "Action Level", 29CFR 1910.1048. Please refer to the OSHA Standard for guidance applicable to your specific operations. Acetone 67-64-1 Ingestion may cause liver damage. Ingestion may cause kidney damage. -- See Footnote C. Toluene 108-88-3 Suspect reproductive hazard. May cause reproductive disorders based on animal data. May cause spleen damage based on animal data. Can cause liver damage. Can cause kidney damage. May cause cardiac sensitization based on animal data. Prolonged and repeated exposures to high concentrations have resulted in hearing loss in laboratory animals. -- See Footnote C. Hexane 110-54-3 Suspect reproductive hazard. May cause male reproductive disorders based on animal data. Chronic exposures may cause peripheral neuropathy. -- See Footnote C. Cyclohexane 110-82-7 May cause lung damage based on animal data. Pre-existing respiratory disorders may be aggravated by exposure. May cause liver damage based on animal data. May cause kidney damage based on animal data. -- See Footnote C. Footnote C: As of the date of issuance of this document, this material has not been listed by NTP, classified by IARC nor regulated by OSHA as a carcinogen.
INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Call a physician. SKIN: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing and shoes before reuse. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held apart during irrigation to insure water contact with entire surface of eyes and lids. Call a physician.
Autoignition Temperature Not determined Upper/Lower Flammable Limits Not determined Up/Lower Explosive Limits, % by Vol 18/1 % Flash Point -104.5°C (-156°F) pensky-martens c.c. EXTREMELY FLAMMABLE LIQUID AND VAPOR. Keep liquid and vapor away from heat, sparks, flame and other ignition sources including, but not limited to, pilot lights, heaters, cigarettes, electric motors and static discharge. Vapor is heavier than air and may settle in low places or travel outward to a source of ignition and flashback. In case of fire, use water fog, dry chemical, foam or CO2. Use water to keep fire-exposed containers cool.
Eliminate all ignition sources. Soak up with absorbent material and remove to a chemical disposal area. Prevent entry into natural bodies of water.
Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). INHALATION: Avoid breathing vapor. Use with adequate ventilation. SKIN: Avoid contact with skin and clothing. EYES: Avoid contact with eyes.
Store in a cool, well-ventilated area. Store in cool, dry area away from sun, heat, oxidizing materials and alkaline materials. Do not store at temperatures above 50 C. Keep away from heat, sparks, flame and other ignition sources.
ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and remote control in combination with appropriate use of personal protective equipment and prudent work practices. These techniques may not necessarily address all issues pertaining to your operations. We, therefore, recommend that you consult with experts of your choice to determine whether or not your programs are adequate. If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria.
Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA laws and regulations or other applicable standards or guidelines, including ANSI standards regarding respiratory protection. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin contact.
Formaldehyde 50-00-0 ACGIH TLV: 0.3 ppm (0.37 mg/m³) Ceiling, A2 - See Appendix A OSHA PEL: 0.75 ppm(0.9 mg/m³) TWA; 2 ppm(2.5mg/m³)15min STEL Acetone 67-64-1 ACGIH TLV: 500 ppm (1188 mg/m³) TWA; 750 ppm (1782 mg/m³) STEL OSHA PEL: 1000 ppm (2400 mg/m³)TWA REMANDED PEL: 750 ppm (1800 mg/m³) TWA; 1000 ppm (2400 mg/m³) STEL OSHA 1989 PEL remanded, but in effect in some states Propane 74-98-6 ACGIH TLV: 2500 ppm (4508 mg/m³) TWA OSHA PEL: 1000 ppm (1800 mg/m³) TWA Toluene 108-88-3 ACGIH TLV: Skin - 50 ppm (188 mg/m³) TWA OSHA PEL: 200 ppm TWA; 300 ppm Ceiling; 500 ppm 10-min STEL REMANDED PEL: 100 ppm (375 mg/m³) TWA; 150 ppm (560 mg/m³) STEL OSHA 1989 PEL remanded, but in effect in some states Hexane 110-54-3 ACGIH TLV: Skin - 50 ppm (176 mg/m³) TWA OSHA PEL: 500 ppm (1800 mg/m³) TWA REMANDED PEL: 50 ppm (180 mg/m³) TWA OSHA 1989 PEL remanded, but in effect in some states Cyclohexane 110-82-7 ACGIH TLV: 300 ppm (1030 mg/m³) TWA OSHA PEL: 300 ppm (1050 mg/m³) TWA Dimethyl Ether 115-10-6 ACGIH TLV: NONE ESTABLISHED OSHA PEL: NONE ESTABLISHED
Percent Volatiles 79 VOC Content 62.2 % pH @ 25 C Not applicable Specific Gravity 0.6928 Appearance Clear amber liquid Autoignition Temperature Not determined Boiling Point -42.2 to 110.6°C (-44 to 231°F) Vapor Density (Air=1) >1 Vapor Pressure, mm Hg @ 20 C Not determined Evaporation Rate (Butyl Acetate=1) >1 Upper/Lower Flammable Limits Not determined Up/Lower Explosive Limits, % by Vol 18/1 % Flash Point -104.5°C (-156°F) pensky-martens c.c. Freezing Point Not applicable Melting point Not applicable Odor Mint when wet Odor Threshold, ppm Not determined Solubility in Water Negligible Coefficient of Water/Oil Distrib. Not determined
Normally stable as defined in NFPA 704-12(4-3.1).
Keep away from combustibles, ignition sources, oxidizers and acids.
Strong oxidizers and reducing agents.
CO, CO2, aldehydes and carboxylic acids.
Will not occur.
None known to company.
See Section 3 Hazards Identification information. Formaldehyde 50-00-0 LC50: rat=590 mg/kg (SAX) LD50: orl-rat=0.8 g/kg (Merck); skn-rbt=0.27 g/kg (Sax) Acetone 67-64-1 LC50: Not available LD50: oral-rat=5800 mg/kg (RTECS); skin-rabbit=20 g/kg (RTECS) Propane 74-98-6 LC50: Not available LD50: Not available Toluene 108-88-3 LC50: Not available LD50: orl-rat=5000 mg/kg; skn-rbt=14 g/kg (Sax) Hexane 110-54-3 LC50: Not available LD50: orl-rat=28700 ug/kg (Sax) Cyclohexane 110-82-7 LC50: Not available LD50: orl-rat=29.82 g/kg (Sax) Dimethyl Ether 115-10-6 LC50: Not available LD50: Not available
Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal requirements. Empty container: May contain explosive vapors. DO NOT cut, puncture or weld on or nearby.
The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. ORM-D Consumer Commodity.
This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "Hazard Communication" Standard.
Fire hazard Immediate health hazard Delayed health hazard
This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. Toluene 108-88-3 10.00% n-Hexane 110-54-3 25.00% Cyclohexane 110-82-7 5.00%
All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. CLASS D, DIV 1B CLASS D, DIV 2B CLASS B, DIV 2
All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements.
This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. Toluene 108-88-3 10.00% Hexane 110-54-3 25.00% Cyclohexane 110-82-7 5.00%
CL (Cautionary Labeling): Products bearing the CL (Cautionary Labeling) Seal of The Art & Creative Materials Institute, Inc. (ACMI) are certified to be properly labeled in a program of toxicological evaluation by a medical expert. This program is reviewed by ACMI's Toxicological Advisory Board. These products are certified by ACMI to be labeled in accordance with the chronic hazard labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695.
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients.
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.
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